大尺寸非线性光学晶体YCOB地研究进展.pdfVIP

(3)光电信息材料与器件 大尺寸非线性光学晶体YCOB 的研究进展 * 武安华 ，郑燕青，徐军，施尔畏 （中国科学院上海硅酸盐研究所，上海， 200050） 摘要：1992 年Norrestam 等人用高温固相反应的方法合成了一系列包括Ca YO(BO ) (简称YCOB) 在内的 4 3 3 钙- 稀土硼酸盐化合物，1997 年Makoto 等人首次用Czochralski 法生长出了YCOB 晶体, YCOB 晶体受到 了国内外晶体生长界的广泛关注。近年来，惯性约束聚变点火工程将YCOB 晶体视作快点火核聚变装置中 频率转换器件中非线性材料的重要候选，大尺寸YCOB 晶体的生长成为其获得重大应用的关键。本文结合 笔者最近几年的研究工作以及国内外YCOB 晶体的生长情况，介绍了YCOB 晶体的生长情况特别是大尺寸晶 体生长的研究进展，并对将来的生长研究的前景进行了展望。 关键词：430.45 ，非线性晶体，晶体生长，YCOB ，激光点火 Progress on research of crystal growth of large size nonlinar optical crystal YCOB WU Anhua, ZHENG Yanqing, XU Jun, SHI Erwei (Shanghai Institute of Ceramics, Chinese Academy of Science,1295 Dingxi Road, Shanghai 200050) Abstract: Norrestam et al. synthsized the isostructural calcium rare-earth oxyborates with solid reaction method in 1992,which include Ca YO(BO ) (.YCOB), Makoto et al. sucessfully grew YCOB crystal with Czochralski 4 3 3 technique in 1997, YCOB crystal has attracted great attentions as nonlinear optical materials. Recently, YCOB crystal is regard as matrial candicate of frequency conversion devices in fast ignition facility, thus it become important science and key technology problem that large size YCOB crystal growth. The crystal gowth of YCOB, specially for large size YCOB crystal, is reviewed based on the research details in the world. It is predicated that large size YCOB crystal growth in the future in this paper. Key words: 430.45, nonlinear optical crystal, crystal growth, YCOB, laser ignition 0引言 近十余年来,用于蓝/绿光和UV波段的非线性光学晶体一直难以得到广泛应用,其中 一个重要的原因是没有开发出大尺寸、低成本的非线性光学