铀矿堆浸过程的动力学模型和实验研究_陈海辉.pdfVIP

铀矿堆浸过程的动力学模型和实验研究_陈海辉.pdf

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34 2 Vol.34 No.2 () 2013 3 Mar. 2013 JournalofJinggangshanUniversity (NaturalScience) 40 40 () 1674-8085(2013 1 * 2 1. 343009 2. 343009 60% 7 -1 8 1.5 10 s 3.6 10 m/s 40% TL212.1+ 1 A DOI:10.3969/j.issn2013.02.009 DYNAMIC MODEL AND EXPERIMENT STUDY OF URANIUM MINE HEAP LEACHING PROCESS 1 * 2 CHEN Hai-hui ZENG Ying-ying 1 School of Chemistry and Chemical Engineering ,Jinggangshan University, Ji’an, Jiangxi 343009,China 2. School of Mechaical and Electrical Engineering, Jinggangshan University, Ji’an, Jiangxi 343009, China) Abstract: The process model and chemical reaction constants of uranium mine sulfuric acid heap leaching are deduced by the relationship curve between the leaching rate and leaching time. The results show when the leaching rate less than 60%, it is linear with the leaching time, and the leaching process model is controlled by -7 -1 chemical reaction process. The chemical reaction leaching rate constant is 1.5 × 10 s , the liquid-solid phase -8 chemical reaction coefficient is 3.6 × 10 m/s in this experimental data. It also shows that if oxidants were not added into the heap-leaching uranium ore, only 40% of the quadrivalent uranium could be oxidized into hexavalent uranium, so the oxidants must be added to improve the oxidizing ability for greater leaching rate of uranium. Key words: heap leaching; uranium; chemical reacti

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