海水飞溅区Cr、Ni对钢的锈层与耐蚀性的影响.pdfVIP

The 6th China Corrosion Conference Influence of Cr and Ni on Rust Layer and Corrosion Resistance of Steels in Marine Splash Zone 1 1 2 Bing HAN , Guiqiao HUANG , Wanling ZHANG 1Qingdao Research Rnstitute for Marine Corrosion, Central Iron and Steel Research Institute, Qingdao, China 2 Technology Centre, Wuhan Iron and Steel (Group) Company, Wuhan, China Email : hanbing@, huangguiqiao@ Abstract: The structure and morphology of the rust layer of steels contained Cr or Ni in marine splash zone were investigated by X-ray diffraction(XRD) and scanning electron microscope(SEM). Influence of Cr and Ni on the rust layer and steels corrosion resistance were Discussed. Results shown that adding 1~2%Cr in the steels did not affect the rust layer phase composition and content obviously, but increased the rust layer com- pactness and corrosion resistance. However, by adding 2~3%Ni, the -FeOOH contents，non-crystallization degree and the compactness in the rust layer were all raised, and as a result signally improved the steels anti- corrosion. Keywords: steel; marine splash zone; rust layer; Cr; Ni 海水飞溅区Cr、Ni 对钢的锈层及耐蚀性的影响* 1 1 2 韩冰 ，黄桂桥 ，张万灵 1 钢铁研究总院青岛海洋腐蚀研究所，青岛，中国，266071 2 武汉钢铁集团公司技术中心，武汉，中国，430080 Email: hanbing@, huangguiqiao@ 摘 要：采用X 射线衍射(XRD)和扫描电子显微镜（SEM ）研究了含Cr 钢和含Ni 钢海水飞溅区锈层 的相组成和微观形貌，讨论了Cr、Ni 对钢锈层及耐蚀性的影响。结果表明，添加 1~2%Cr 对钢锈层的 相组成及其含量无明显影响，但提高了钢锈层的致密度，使钢的耐蚀性略有提高。添加 2~3%Ni 使钢 锈层中-FeOOH 的含量明显增加、非晶化程度提高，钢锈层的致密度提高，从而使钢的耐蚀性显著提 高。 关键词：钢；海水飞溅区；锈层；Cr；Ni