三维凹凸棒疏水材料的制备及其吸附性能.pdfVIP

第 卷第 期 38 2 Vol.38 No.2 非金属矿 2015 年3月  Non-Metallic Mines March, 2015 三维凹凸棒疏水材料的制备及其吸附性能 梁卫东  王  睿  陈品松  王源瑞  吴  叶 （兰州理工大学 石油化工学院，甘肃 兰州 730050） 摘  要  采用溶液聚合法制备聚丙烯酰胺/ 凹凸棒(PAM/ATP) 复合吸附材料，经冷冻干燥处理、氮气保护条件下高温碳化制备出三维网络凹 凸棒复合材料(APM) ，通过聚二甲基硅氧烷(PDMS) 的化学气相沉积(CVD) 有机改性APM 得到三维凹凸棒疏水材料(PAPM)。采用XRD、SEM、 BET、FT-IR 等多种方法进行了表征，结果显示，PAM 成功接枝到ATP 表面，且APM 表面疏松多孔；平均孔径从ATP 的9.105 nm 增加至APM 的 11.205 nm ；PDMS 成功改性APM ，与ATP 相比，PAPM 对有机物的吸附量增大6 倍以上，表明PAPM 是一种良好的油/ 水分离吸附材料，具有选择 性吸附性能。 关键词 凹凸棒；冷冻干燥；三维网络；选择性吸附；聚二甲基硅氧烷 TB34;TD985 A 1000-8098(2015)02-0011-04 中图分类号： 文献标识码： 文章编号： Preparation and Adsorption Properties of Three Dimensional Attapulgite Hydrophobic Material Liang Weidong Wang Rui Chen Pinsong Wang Yuanrui Wu Ye (Institute of Petrochemical Technology, Lanzhou University of Technology, Lanzhou, Gansu 730050) Abstract In this work, three dimensional attapulgite hydrophobic material (PAPM) was synthesized by using solution polymerization, freeze- drying method, thermolysis treatment and modification with polydimethylsiloxane (PDMS). Then, the samples were investigated by XRD, SEM, BET, FT-IR and other methods. Observation showed that the polypropylene amide (PAM) was successfully grafted onto the surface of the attapulgite (ATP) and the three dimensional network attapulgite composite (APM) was the spongy structure. The average pore size increased from 9.105 nm of ATP to 11.205 nm of APM. The APM was successfully modified by using PDMS, which was characterized by FT-IR. It was found that organi