Photocatalytic removal of water in the Evaluation of dibutyl phthalate.docVIP

 PAGE \* MERGEFORMAT 12 Photocatalytic removal of water in the Evaluation of dibutyl phthalate 【Abstract】 Objective To study the photocatalytic removal of a continuous flow, dibutyl phthalate (DBP) results. Methods to set 4 different flow rate of water flow 25,65,110,190 ml / min. Conducted using four kinds of processing capacity O3 (produced by the ozone generator after the gas flow of 0  6L/min); ultra-violet (UV) irradiation; UV radiation at the same time pass O3; UV-pass the air at the same time. In the bright nano-catalyst (TiO2) and without catalyst under the conditions to carry out photolysis experiments Determination of dibutyl phthalate removal. The results of TiO2 can promote the rapid photolysis of DBP, flow rate at 190ml/min when, DBP removal rate could reach 88  8%. Pass the air little effect on the UV light degradation, and even reduce the removal rate. UV and ozone together on the degradation of DBP have a certain synergy. Conclusion photocatalytic water can be effective in a continuous degradation of dibutyl phthalate in water. Keywords: Photocatalysis Dibutyl phthalate (DBP) are phthalic acid esters, is an environmental endocrine disruptors. Mainly used as a plasticizer added to plastics to increase flexibility 〔1〕. Phthalates are not chemically combined in polyvinyl chloride (PVC) polymer or other materials, they may be in use during or after the waste leaking from a product out on aquatic life interfere with endocrine effects 〔2 , 3〕. We have detected in tap water DBP, the highest concentration for 11  1μg / L 〔4〕. In the past study, we have reported progress of DBP degradation of 〔5〕 and in the static photocatalytic degradation of water 〔6〕. In this paper, continuous-flow approach for removal of organic pollutants in DBP, which approach makes more sense in the application. 1 Materials and methods 1  1 experimental materials dibutyl phthalate (DBP), were of analytical grade (Beijing Chemical Reagent Com