第三讲(烯烃光化在学)-2012.ppt

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第三讲(烯烃光化在学)-2012.ppt

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第三讲(烯烃光化在学)-2012

Refs Tetrahedron Lett. 2006, 47, 733 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 烯烃光化学 Part I 分子内反应 1）顺-反异构化反应 2）环合反应 Part II 分子间反应 4）与溶剂的加成反应 3）重排反应 5）二聚反应 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 1）顺－反异构化反应 Part I Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 烯烃光异构化机理直接光照：产生 S1 (?, ?*) 态，异构化发生在 S1 (?, ?*)势能面上敏化作用：产生 T1 (?, ?*)态，异构化发生在 T1 (?, ?*) 势能面上 Part I Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 降冰片【2＋2】分子内环合加成反应上述反应可直接通过光照经由 S1 态完成，也可通过光敏化反应由 T1 态完成。敏化剂的能量对平衡转化率有显著的影响。降冰片四环烷 Part I 2）环合反应 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Part I Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 香叶烯的直接光照和敏化反应产物 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 3）重排反应 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Part I Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 例 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 20