Benzene Oxidation on Boron-Doped Diamond Electrode Electrochemical-Impedance Study of Adsorption Effects英文文献资料.docVIP

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Benzene Oxidation on Boron-Doped Diamond Electrode Electrochemical-Impedance Study of Adsorption Effects英文文献资料.doc

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Benzene Oxidation on Boron-Doped Diamond Electrode Electrochemical-Impedance Study of Adsorption Effects英文文献资料

HindawiPublishingCorporation InternationalJournalofElectrochemistry Volume2012,ArticleID437063,9pages doi:10.1155/2012/437063 ResearchArticle BenzeneOxidationonBoron-DopedDiamondElectrode: Electrochemical-ImpedanceStudyofAdsorptionEffects YuriPleskov,MarinaKrotova,ValeriiElkin,ValentinVarnin,andIrinaTeremetskaya FrumkinInstituteofPhysicalChemistryandElectrochemistry,RussianAcademyofSciences,Leninskiipr.31,119991Moscow,Russia CorrespondenceshouldbeaddressedtoYuriPleskov,pleskov@electrochem.msk.ru Received29March2011;Revised24May2011;Accepted25May2011 AcademicEditor:CarlosAlbertoMartinez-Huitle Copyright?2012YuriPleskovetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense, whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited. Benzeneoxidationataboron-dopeddiamondanodein0.5MK2SO4 aqueoussolutionisstudiedbycyclicvoltammetryand electrochemicalimpedancespectroscopy.Itisshownbymeasurementsofdi?erentialcapacitanceandanodiccurrentthatinthe ideal-polarizabilitypotentialregionbenzeneeitherisnotadsorbedatthediamondelectrodeorthebenzeneadsorptiondoesnot a?ectitscapacitance.Atmorepositivepotentials,theadsorptionofsomeintermediateofthebenzeneoxidationoccursatthe electrode.Theintermediatepartiallyblockstheelectrodesurfaceandlowerstheanodiccurrent.Theveryfactoftheelectrode surfaceblockingisre?ectedinthecomplex-planepresentationoftheimpedance-potentialplots. 1.Introduction thebenzeneoxidationintermediates(hydroquinone,resor- cinol, p-benzoquinone, catechol, and phenol) was formed insolutionattheanodepotentialof2.5V(versusAg/AgCl- electrode). The benzene complete incineration yielding CO2 occurs at potentials more positive than 2.5V. In our precedingpaper[6],thebenzeneoxidationatboron-doped diamondanodewasstudiedin1MHClsolutionbyelectro- chemicalimpedancespectroscopy,withspecialemphasison therevealingoftheroleofadsorptionintheprocess. In this work, the benzene oxidation at boron-doped diamondanod