Calculation of the pH of Buffer Solution of 2-[N -Morpholino]ethanesulfonic Acid (MES) from 5°C to 55°C英文文献资料.docVIP

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Calculation of the pH of Buffer Solution of 2-[N -Morpholino]ethanesulfonic Acid (MES) from 5°C to 55°C英文文献资料.doc

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Calculation of the pH of Buffer Solution of 2-[N -Morpholino]ethanesulfonic Acid (MES) from 5°C to 55°C英文文献资料

Open Journal of Physical Chemistry, 2011, 1, 77-84 77 doi:10.4236/ojpc.2011.13011 Published Online November 2011 (http://www.SciRP.org/journal/ojpc) Calculation of the pH of Buffer Solution of 2-[N-Morpholino]ethanesulfonic Acid (MES) from 5?C to 55?C Lakshmi N. Roy, Rabindra N. Roy*, Joshua T. Wollen, Jessica M. Stegner, Meagan A. Harmon, Michael S. Martin, Blake M. Bodendorfer, Isaac B. Henson Hoffman Department of Chemistry, Drury University, Springfield, USA E-mail: rroy@ Received June 22, 2011; revised August 7, 2011; accepted September 15, 2011 Abstract This paper reports the results for the pH of three buffer solutions free of chloride ion. The remaining six buffer solutions have saline media of the ionic strength I = 0.16 mol·kg , matching closely to that of the physiological sample. Conventional paH values for the three buffer solutions without the chloride ion and six buffer solutions with the chloride ion at I = 0.16 mol·kg from 5?C to 55?C have been calculated. The opera- –1 –1 tional pH values for five buffer solutions at 5 ?C and 55?C have been determined based on the difference in the values of the liquid junction potentials between the blood phosphate standard and the experimental buffer solutions. Five of these buffers are recommended as standards for the physiological pH range 7.5 to 8.5. Keywords: Buffers, MES, BICINE, Liquid Junction, Ionic Strength, Emf, pH 1. Introduction physiological phosphate pH buffer as a primary standard [4]. The phosphate buffer has been widely used as a phy- siological pH standard, but it is not an ideal primary pH standard buffer for physiological use at an ionic strength –1 of I = 0.16 mol·kg . The disadvantages are as follows: 1) phosphates act as inhibitors to enzymatic processes; 2) phosphate precipitates occur with some polyvalent The buffer substances recommended by Good et al. [1-3] have proven very useful for the measurement of the pH of blood and the control