ZSM-5沸石填充聚氨酯膜的制备及渗透汽化分离水中乙酸异丙酯.pdfVIP

学兔兔 化 工 进 展 2011年第30卷第9期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·1919· ZSM一5沸石填充聚氨酯膜的制备及渗透汽化分离 水中乙酸异丙酯 白云翔，杨 乐，顾 瑾，邹 超，张春芳，孙余凭 (江南大学化学与材料工程学院，江苏 无锡 214122) 摘 要：采用两步法制备了ZSM一5沸石填充的疏水性端羟基聚丁二烯基聚氨酯 (PU)膜，用以分离水中芳香性 有机物乙酸异丙酯。对该膜的化学结构、形貌及热稳定性进行了表征，并研究了ZSM一5沸石填充的PU膜的溶 胀度及渗透汽化性能。结果表明：添加ZSM一5沸石后，膜的热稳定性明显提高，沸石与膜的相容性较好，且随着添 加量的增加，膜的~-ff-／!I_降低，分离因子先升后降。在303 K、料液浓质量分数为1％的条件下，ZSM一5添加量为 20％(质量分数)时，分离因子达到最高；同时随着料液一Z度一 o，。P，皿-~度的上升，通量和分离因子都增加。在333K、 料液质量分数为1％的条件下，Pu—ZSM一5—20膜的分离因子及通量最高可达288．72 (m0．h)和53．21 g／(m2．h)。 关键词：聚氨酯膜；ZSM一5；渗透汽化；乙酸异丙酯 中图分类号：TQ 028．8 文献标志码：A 文章编号：1000—6613(2011)09—1919—07 ZSM-5-filled HTPB—based polyurethane membranes for perVap0ratiOn separation of isopropyl acetate／water mixtures BAIYunxiang，YANGLe，GUJin，ZOUChao，ZHANGChunfang，SUNYuping (School of Chemical and Material Engineering，Jiangnan University，Wuxi 214122，Jiangsu，China) Abstract：ZSM．5．filled hydroxyl terminated polybutadiene(HTPB)一based polyurethane(PU) membranes(PU—ZSM一5)，were prepared by a two—step polymerization process，and were used as membrane material to recover，isopropyl acetate(IPIAC)，from aqueous solution by pervaporation(PV)． The chemical structure，morphology and thermal stability of these filled membranes were characterized． The effects of ZSM一5 content on swelling degree and pervaporation performance were investigated． The results indicated that the incorporation of the ZSM．5 improved the thermal stability of the membranes apparently was compatible with the membranes．The swelling degree of the ZSM一5一filled PU memb