Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water 英文参考文献.docVIP

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Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water 英文参考文献.doc

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Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water 英文参考文献

Polymers 2011, 3, 621-639; doi:10.3390/polym3010621 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water Toshimasa Suzuka *, Kosuke Kimura and Takuya Nagamine Department of Chemistry, Biology Marine Science, University of the Ryukyus, Okinawa 903-0213, Japan; E-Mails: e073309@eve.u-ryukyu.ac.jp (K.K.); e073332@eve.u-ryukyu.ac.jp (T.N.) * Author to whom correspondence should be addressed; E-Mail: suzuka@sci.u-ryukyu.ac.jp; Tel.: +81-98-895-8531; Fax: +81-98-895-8531. Received: 10 January 2011; in revised form: 8 February 2011 / Accepted: 9 March 2011 / Published: 14 March 2011 Abstract: A novel heterogeneous transition-metal catalyst comprising a polymer-supported terpyridine palladium(II) complex was prepared and found to promote the Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost, reactions in water under aerobic conditions with a high to excellent yield. The catalyst was recovered by simple filtration and directly reused several times without loss of catalytic activity. Keywords: palladium; terpyridine; cross-coupling; polymer-supported synthesis 1. Introduction Palladium-catalyzed reactions that form carbon-carbon bonds, such as Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost cross-coupling, are of considerable importance in organic chemistry [1-11]. These cross-coupling reactions are generally catalyzed with soluble palladium complexes in an organic solvent or in a mixture of water and an organic solvent [12-15]. However, there has been a continuing challenge with such catalyst systems regarding their efficient separation and recycling, which are important considerations for economic and ecological reasons. Heterogeneous palladium-catalyst systems have been found to be highly effective for overcoming some of these