Cu-RE-Al2O3催化剂上CO2加氢制甲醇-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第8期 PETROCHEMICAL TECHN0L0GY ·941· Cu—RE—AI2O3催化剂上CO2加氢制甲醇 赵锦波 ，于 杨 (1．中国石油化工股份有限公司 科技部，北京 100728；2．中国石化 南化集团研究院，江苏 南京 210048) [摘要]采用共沉淀法制备了稀土元素(RE=Y，La，Ce，Dy或Ho)掺杂的cu基催化NCu．RE．A1 O，(简称CREA)，考察了催 化剂在CO，加氢制甲醇反应中的催化性能和水热稳定性，并在Cu—La—A1 O (CLA)催化剂上，考察了反应温度和原料空速对反 应的影响；采用XRD、N：O分解、H：一TPR、CO 一TPD、Raman光谱等方法分析了催化剂的“构效关系”。实验结果表明，在 CREA催化剂中，CLA催化剂具有较高的CO 转化率、甲醇选择性和水热稳定性；CLA催化剂上CO：加氢制甲醇的最佳反应温 度为240℃；原料空速的增加导致CO：转化率和甲醇选择性均下降；还原后CREA催化剂上cu比表面积越大、吸附co 碱性位 数量越多，催化剂的活性越高；CREA催化剂中CuO晶格畸变和无序程度越高，催化剂的甲醇选择性越高。 [关键词]稀土元素；铜基催化剂；二氧化碳加氢；甲醇 [文章编号]1000—8144(2014)08—0941—07 [中图分类号]TQ 223．121 [文献标志码]A CO2 Hydr0genati0n to Methanol over Cu-RE-AI203 Catalyst Zhao Jinbo ，Yu Yang2 (1．S1NOPEC Science and Technology Department，Beijing 100728，China； 2．SINOPECResearchInstitute ofNanjingChemicalIndustryGroup，Nanjing Jiangsu 210048，China) [Abstract]Cu—RE—A1203(CREA，RE：Y，La，Ce，Dy or Ho)catalysts were prepared through CO-precipitation．Their catalytic performance and hydrotherm al stability in the hydrogenation of CO2 to methanol were investigated．The effects of reaction temperature and space velocity of feed gas on the hydrogenation over the Cu—La-A12O3(CLA)catalyst were studied．The relationship between the structure and perform ances of the CREA catalysts was analyzed by means of XRD，N2O decomposition，H2一 TPR，CO2~TPD and Raman spectra．The results showed that the CLA catalyst displayed the highest CO2 conversion，methanol selectivity and hydrothermal stability．For the hydrogenation over the CLA catalyst，the optimum reaction