高性能形状记忆透明聚氨酯的制备与研究.pdf

第29卷第3 期 化 学 研 究 与 应 用 ^ Vol .29,No .3 2017年3 月 Chemical Research and Application Mar. ,2017 文章编号：1004-1656 (2017) 03 -0425-04 高性能形状记忆透明聚氨酯的制备与研究 张 军 瑞 蒋 国 军 \ 俞 卫 华 2 (1.浙江工业大学之江学院理学院，浙 江 绍 兴 ，312030; 2.浙江工业大学信息工程学院，浙 江 杭 州 ，310014) 摘要:以市售羟基丙烯酸树脂和异氰酸酯为主要原料，通过聚己内酯二醇的加人制备出一系列具有形状记忆 效应的透明聚氨酯薄膜,同时其形变恢复温度可进行连续可控调节。对聚氨酯薄膜的形变恢复温度和形状记 忆效应进行了测定，并对其形状记忆功能进行了表征。研究结果表明羟基丙烯酸树脂和聚己内酯二醇制备的 聚氨酯都具有形状记忆功能,羟基丙烯酸树脂制备的聚氨酯具有较高的形变恢复温度且室温较脆;聚己内酯 二醇制备的聚氨酯具有较低的形变恢复温度，室温较软;通过将羟基丙烯酸树脂和聚己内酯二醇进行合理的 配比可制备出在此温度区间连续可调的具有形状记忆效应的透明聚氨酯；同时当体系中聚己内酯二醇的含 量较高时，聚氨酯变形后在室温的定型效果较差。 关键词:羟基丙烯酸树脂;聚己内酯二醇;聚氨酯;形状记忆 中图分类号:〇633. 12 文献标志码:A Synthesis and study of high performance shape memory transparent polyurethanes films Z H A N G Jun -rui1* , JIANG Guo -jun1 ,YU Wei -hua2 (1. School of Science,Zhijiang College of Zhejiang University of Technology,Shaoxing 312030,China ； (2. College of Information Engineering,Zhejiang University of Technology,Hangzhou 310014,China ) Abstract A： series of shape memory transparent polyurethane films were synthesized with commercially available hydroxyl acrylic resin and isocyanate,and its glass transition temperature( Tg^^ould be controlled continuously. The recovery temperature and shape memory effect of polyurethane films were determined , and their shape memory function was characterized. The results showed that polyurethanes prepared with hydroxyl acrylic resin and polycaprolactone diol all had shape memory effect. Polyurethanes synthesised with hydroxyl acrylic resin had higher Tg and they were brittle at room temperature; Polyurethanes synthesised with polycaprol