五不同形态硫化合物对环烷酸腐蚀的影响.ppt

内容;第五节 不同形态硫化合物对环烷酸腐蚀的影响 ;1 硫化合物的分类;活性硫;2 硫和环烷酸的相互作用;3 硫化合物对环烷酸腐蚀的影响;原油类型;4 硫化氢对环烷酸腐蚀的影响;Regardless of the high dispersion found, the fact that such theoretical points are very near to the experimental ones, at lower concentrations of H2S, possibly indicates that the iron naphthenate produced through (1), is reacting with the hydrogen sulfide through (3). Only at higher H2S concentrations (i.e. 7.5%) does reaction (2) prevails over reaction (1). In other words, reaction (1) is faster than (2) at relative lower H2S concentration, whereas reaction (2) is faster than (1) at higher H2S concentrations. As a consequence, hydrogen sulfide has no inhibitor effect toward naphthenic acid corrosion at lower H2S concentrations. On the contrary, lower H2S concentrations consume iron naphthenates, accelerating (1). At higher H2S concentrations, there is a deviation from the behavior where reaction (3) predominates. In this sense, at 7.5% of H2S, the theory predicts 638 ppm of dissolved iron, but just 50 ppm were found (see Fig. 1), which corroborates that reaction (2) is faster than (1), a protective layer of FeS is formed and this preventfurther attack by the naphthenic acid. ;5 硫醇硫对环烷酸腐蚀的影响;;5 硫醇硫对环烷酸腐蚀的影响;6 二硫化物对环烷酸腐蚀的影响;;;9 硫化合物影响环烷酸腐蚀的机理;10 与A原油反应后铁粉表面硫的形态;;11 不同原油的S-O伸缩带;12 不同原油混合结果;Table 3 Iron Powder Test results for different crude oils, plus its %S, TAN, maximum dissolved iron allowed by its TAN and its efficiencies;13 小结; 二硫化物的减缓效应更加明显，在≥220 ℃的温度下，环烷酸的腐蚀完全被抑制。 噻吩以及砜难以被氢还原，它们的加入对环烷酸腐蚀无影响。 硫化合物容易被腐蚀过程中产生的质子还原，当还原产物是 H2S时，产生的FeS膜将会减缓环烷酸的腐蚀，但是，当在环烷酸腐蚀的阴极带有还原产物H2O时，环烷酸有可能进一步离解，此时，阴极反应进一步增加，同时也增加了环烷酸的腐蚀。但温度进一步升高时，产生的水进一步与环烷酸铁反应；亚砜还原产生的硫化氢与铁反应生成硫化铁膜，原油中亚砜的分析和定量对于确定环烷酸的腐蚀是非常重要的。如果存在这??硫化合物，环烷酸腐蚀的加剧程度一定要引起足够重视。;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;目 录;高酸原油特性与问题;炉管结垢 馏分油金属含量超标 装置腐蚀 废水难处理 ;钙盐存在形态 有机钙 无机钙 化学法脱钙原理 油水混合 界面反应 油水分离;原油脱钙剂RPD-Ⅱ特点 ;Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspo