催化动力学光度法测定痕量钒(Ⅴ).pdfVIP

沈阳工业大学学报 Vo1.28 No.4 第 28 卷第 4 期 2006 年 8 月 lournalof 2006 文意编号: 1000 一 1646(2∞6)04 - 0478 - 03 催化动力学光度法测定痕最饥(V) 赵丽杰，赵丽萍 (沈阳工业大学石化学院，辽宁辽阳 111003) 摘 襄:在硫酸介质中，以抗坏.I!n.酸为活化剂，对饥催化澳酸饵氧化中性枉的反成进行了研究，建立 了一种测)E痕量饥的新方法.对被长、介质、增敏刑、反应温服及时间进行了测词，得出了最佳试验条 件:试荆加入分别为1.ωX 10- 3 rllL中性红溶液0.50 mL;5 x 10ω2tmlIL 的硫酸溶液1.2 mL;5 x 盯 10血与rllL的抗坏血酸榕液0.2 mL;1.佣 x 10…2rmllL澳酸御溶液1.2 mL及造最饥;在沸水播中加 热 16 min，在 525nm披长处测定.该方法的线性榄嗣为0-0.6 周矶，检出限为1.42 x 10-11 g/mL，最 大相对标准偏差为0.82%. 该方法用于湖水中痕最饥的测定，阴收率在96.0% -104.5%之间. 提键诩:催化动力学光度法;澳酸仰;中性红;饥;水样 中阳分类号: 0657.32 文献标识码:A Detem血mtion of 衍酣Vanadimn( V) using catalytic kinetic 句附trophot侧削叮 ZHAO Lì-jie , ZHAO Lì匍柿?阳 ( Institute of Petro时10时01沁eum盯mandCαh衍m旧C创且a.lEn咿g原阴in阳e倪eeri咱. Shenyang University of Technol咽 Liaoyang 111003 , China) Abstract: A new catalytic kìnetìc spectrophotometry for determining trace 缸nount of pentavalent vanadium ion was pro仰配d. 丁he method is based on the catalytic effect of Vanadium on the oxidation of neutral red by KBIÛ3 in a medium of Hz创14 in the presence of ascorbic acid as an activator. The influence of measuring wavelength , medium , activator , temperature and time of reaction , and measured absorbance were tested. The optimum experimental conditions are as follows. The applied solution is com阳sed of 0.5 mL neutral red of 1.00 x 10 伽 3 mol lL, 1.2 mL sulfuric acid of 5 x 10命与1011L， 0.2 mL a削rbic acid of 5 x 10…3 口1011L， 2 1.2 mL potassium bromate of 1.00 x 10- mol lL and trace amount of pentavalent vanadium ion. The temperatu