铕离子掺杂类普鲁士蓝复合铋膜电极阳极溶出法测定痕量锌.pdfVIP

西北师范大学学报(自然科学版) 第46卷ZOIO年第4期 62 ofNorthwestNormal Science) V01．462010No．4 Journal University(Natural 铕离子掺杂类普鲁士蓝复合铋膜电极 阳极溶出法测定痕量锌 马永钧，杨海青，彭 波，王伟峰，杨梅霞 ，潘玉莹 (西北师范大学化学化工学院，甘肃省高分子材料重点实验室，甘肃兰州 730070) 摘 要：采用预镀铋电化学沉积法制备了铕离子掺杂类普鲁士蓝复合铋膜电板，建立了阳极溶出伏安法测定痕量锌的 新方法．结果表明，锌在0．03 一1．4V富集120s后，锌的溶出峰电流与其浓度在10～540 99．3％～101．2％． 关键词：锌的测定；复合铋膜电极；溶出伏安法；类普鲁士蓝 中围分类号：0657．1；O614．24+1 文献标识码：A Determinationoftracezinc anodic by strippingvohammetry onPB——Eu bismuthfilmelectrode composite MA Bo，WANG Mei—xia，PAN Yong-jun，YANGHai—qing，PENG Wei—feng，YANG Yu—ying of MaterialsofGansuProvince， (KeyLaboratoryPolymer of andChemical Normal CollegeChemistry Engineering。NorthwestUniversity，Lanzhou bismuthfilm ex-situ Abstract：A electrode(GC／Eu—PB／BFE)is composite preparedby on blue modifiedcarbon bismuththe europium—dopedprussiananalogue(Eu—PB)filmglassy the showthat newmethodforthedeterminationofzincisdevelopedusingGC／Eu—PB／BFE．Theresults thesensitive ofzincionsisobtainedin0．03mol·L一1tartrate strippingpeak the ofzincionsareobtainedintheconcentrationof10--一540 optimumconditions，thegoodlinearity range 120S at一1．4V．Thelimitofdetectionis 弘g·L’1(r=O．99987)afterdoposition and error methodhasbeen tothedeterminationofzincin relativestandardsiS0．94％(，l=8)．The applied andm