高纯lanixalx合金成分及杂质元素的分析方法ananalysis.pdf

CNIC-01507 CAEP-0057 高纯LaNi5--xAlx 合金成分 -- 及杂质元素的分析方法 AN ANALYSIS METHOD FOR COMPOSITIONS AND IMPURITIES IN HIGH-PURITY LaNi5--xAl ALLOY -- x (In Chinese) 中 国 核 情 报 中 心 China Nuclear Information Centre CNIC-01507 CAEP-0057 高纯LaNi - Al 合金成分 5 x x 及杂质元素的分析方法 刘 勇 魏彦波 王怀胜 沈 岚 ( 中国工程物理研究院，成都，610003) 摘 要 叙述了镧―镍―铝（LaNi5-xAlx ）合金成分中镍、铝及微量杂 质元素锌、铁、锰、镁、硅、铜和钙的 ICP-AES 测定方法。样品 以HNO3(1+1)溶解，稀释后直接测定主量元素镍和铝；用基体匹配 法补偿基体效应测定其他杂质元素。各元素回收率为 95%～100%， 相对标准偏差优于5%。 1 An Analysis Method for Compositions and Impurities in High-Purity LaNi --xAl Alloy 5-- x (In Chinese) LIU Yong WEI Yanbo WANG Huaisheng SHEN Lan (China Academy of Engineering Physics, Chengdu, 610003) ABSTRACT A study of analysis method (ICP-AES) for determination of high content components Ni，Al and impurities Fe ，Cu，Zn ，Ca，Mn ，Mg，Si in LaNi5-xAl alloy x is reported. The sample was dissolved by HNO3 (1+1). After diluted, the high content components Ni and Al were determined directly. The matrix matching method was used to correct the matrix effect, then the impurities were determined with ICP spectromet