再论铁系高温变换催化剂的热力学稳定性.pdfVIP

第35卷 第1期 化肥工业 2008年2月 再论铁系高温变换催化剂的热力学稳定性 吕待清 (上海化工研究院 200062) 摘要 在前文…的基础上，进一步对铁系高温变换催化剂在各种不同的变换原料气气氛中的热力学稳定性 进行了具体的分析和计算。结果表明，对于铁系高温变换催化剂，考虑到尽量减少补充水蒸气的要求，其适宜的 入炉水气比的确定应考虑Fe…O C H体系中催化剂保持热力学稳定的Fe O 物相的需要，并同时考虑变换反应化 学平衡的需要。同时指出，铁系高温变换催化剂所需的适宜水气比与原料气的干基组成(CO，H2和CO：)或原料 气(干基)的IB值[IB=( ·yII1)／Yc。 ]及原料气入炉温度有直接关系。 关键词 铁系高温变换催化剂 热力学 稳定性 分析 Another Discussion on Thermodynamic Stability of Iron-Based High Temperature Shift Catalyst Lu Daiqing (Shanghai Research Institute of Chemical Industry 200062) Abstract On the basis of the previous article ¨concrete analysis and calculation of the thermo— dynamic stability of the iron—based high temperature shift catalyst are carried out further in different shift feedgas atmospheres．The results indicate that，as regards the iron—based high temperature shift catalyst，taking into account the requirement to reduce as much as possible steam make—up，the suit— able water—gas ratio into the converter depends on the need for Fe3 O4 phase to keep the catalyst in the Fe·-O·-C·-H system thermodynamically stable and also the need for chemical equilibrium of the shift re·- action．It is pointed out that the suitable water—gas ratio required by the catalyst is related directly to the dry basis composition(CO，H2 and CO2)ofthe feed gas or the value[ =(yco·yH，)／yco，]of the feed gas(dry basis)and the temperature of the feed gas going into the converter． Keywords iron—based high temperature shift catalyst thermodynamics stability analysis 本文则针对由几种不同的制气原料制得的组 O 前言 成不同的原料气，对铁系高温变换催化剂在这些 笔者曾根据热力学有关原理，对铁系高温变 原料气气氛中的热力学稳定性进行进一步的分析 换