不同的Cu-Co比对Cu-Co-Ce-Zr-O催化剂的低温CO氧化活性的影响.docVIP

不同的Cu/Co比对Cu-Co/Ce-Zr-O催化剂的低温CO氧化活性的影响 摘要：本论文以硝酸铜、硝酸钴、硝酸铈和硝酸锆为原料采用共沉淀法制备了Ce0.6Zr0.4O2 固溶体，以此作为载体并采用等体积浸渍法制备了一系列CuxCo1-x /Ce0.6Zr0.4O2 催化剂，利用X射线衍射(XRD)、程序升温还原(H2-TPR)等技术手段对所制备催化剂的晶相结构和表面分散状况进行了分析，最后采用色谱流动法考察了所制备催化剂的CO低温氧化特性。实验结果表明，当Co掺杂量为0.05时，Cu0.95Co0.05/Ce0.6Zr0.4O2催化剂的CO氧化活性最高。四种催化剂催化活性的大小次序为：Cu0.95Co0.05/Ce0.6Zr0.4O2＞Cu0.9Co0.1/Ce0.6Zr0.4O2＞Cu0.75Co0.15/ Ce0.6Zr0.4O2。说明适当掺杂量的Co有利于催化剂氧化活性的提高。5100 关键词：浸渍法；催化活性；低温氧化；还原特性 Effect of different Cu/Co ratio of Cu-Co/Ce-Zr-Ocatalyst on low-temperature CO oxidation activity Abstract: By using copper nitrate, cobalt nitrate, as initiative materials, this paper takes co-precipitation method to produce the solid solution of Ce0.6Zr0.4O2. By the method of isometric impregnation, the solid solution is taken as the carrier to produce a series of catalyst of CuxCo1-x/Ce0.6Zr0.4O2. This paper analyzes the ceramic catalyst and surface dispersion with the technology of XRD, H2-TPR, and so on. It finally resorts to the mobile chromatography to study the oxidative characteristics under low temperature. The experimental result turns to be that when doping amount of Co is 0.05, the oxidative activity of CO is the highest among Cu0.95Co0.05/Ce0.6Zr0.4O2 catalyst. The activity of four catalysts is ranked from high to low as follows: Cu0.95Co0.05/Ce0.6Zr0.4O2＞Cu0.9Co0.1/Ce0.6Zr0.4O2＞Cu0.75Co0.15/Ce0.6Zr0.4O2 which means that appropriate doping amount of Co is in favor of the improvement of oxidative activity of catalyst. Keywords: impregnation method；catalytic activity；oxidation for low-temperature；reduction property 1.3方案论证 通过查阅文献，经过一系列的比较，采用浸渍法制备Cu-Co/Ce-Zr-O催化剂催化氧化CO。之所以选择Cu-Co/Ce-Zr-O作为催化剂，原因是它具有以下优点： 1).通过文献查阅知道采用浸渍法制备的Cu-Co/Ce-Zr-O用XRD和TEM分析表明所制备的CeO2呈球形，为立方萤石结构，CuO在一定程度上高度分散于载体CeO2上，TPR结果证实了Cu-Co/Ce-Zr-O催化剂的活性较高，且远远高于CuO和CeO2。当CuO的负载量达到5.0%时，催化剂具有较高的表面能和最佳的CO氧化活性。其他的非贵金属催化剂都没有Cu-Co/Ce-Zr-O的催化性能好。 2).CeO2在催化剂中起分散剂的作用，可以提高催化剂中金属活性组分的高度分散性能，增进催化剂的热稳定性和抗烧结能力，CeO2还可以提高此类催化剂的储氧能力，使催化剂的储氧量增加，活性提高。 3).采用浸渍法制备的催化剂，活性组分多数情况下仅仅分布在载体