non-equilibrium thermodynamic analysis of transport properties in the nanofiltration of ionic liquid-water solutions纳滤的非平衡热力学传输特性的分析离子液体水的解决方案.pdfVIP

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non-equilibrium thermodynamic analysis of transport properties in the nanofiltration of ionic liquid-water solutions纳滤的非平衡热力学传输特性的分析离子液体水的解决方案.pdf

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non-equilibrium thermodynamic analysis of transport properties in the nanofiltration of ionic liquid-water solutions纳滤的非平衡热力学传输特性的分析离子液体水的解决方案

Molecules 2009, 14, 1781-1788; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Non-Equilibrium Thermodynamic Analysis of Transport Properties in the Nanofiltration of Ionic Liquid-Water Solutions Bo Wu, Yu M. Zhang and Hua P. Wang * State Key Laboratory for Modification of Chemical Fiber and Polymer Materials, Donghua University, Shanghai 201620, China * Author to whom correspondence should be addressed; E-mail: ncuwubo@ Received: 1 April 2009; in revised form: 18 April 2009 / Accepted: 27 April 2009 / Published: 11 May 2009 Abstract: The nanofiltration of aqueous solutions of the ionic liquids (ILs) 1-butyl-3- methylimidazolium tetrafluoroborate ([Bmim]BF4), and 1-butyl-3-methylimidazolium bromide ( [Bmim]Br) with a polyamide nanofiltration membrane was investigated. The practical transport coefficients, including hydrodynamic permeability (Lp), reflection (σ) and solute permeability (ω) were calculated in terms of a non-equilibrium thermodynamics approach. It was found that Lp and σ diminished as the concentration of the IL solutions increased. These characteristics are similar to those observed in inorganic electrolyte-water systems. In addition, it was shown that the rejection and volume flux for both ionic liquid solutions rose with feed pressure, while it decreased with feed concentration. The maximum rejection efficiencies for [Bmim]Br and [Bmim]BF4 are