改性纳米sio2复合uv固化树脂的制备及性能分析 preparation and performance analysis of uv-curable composite resin with modified nano-sio2.pdfVIP

中国印刷与包装研究2012年第2期(第4卷) 研究论文 PRINTINGANDPACKAGINGSTUDYV01．04No．22012．4 RESEARCHPAPERS CH卫、iA 余明光，陈广学，陈奇峰，黄文涛 (华南理工大学制浆造纸工程国家重点实验室，广州510640) 摘要本研究利用正硅酸乙酯、无水乙醇等的水解反应制备纳米SiO：醇溶胶，并用硅烷偶联剂WD一20对所得Si0： 溶胶进行表面改性，真空干燥去除剩余的乙醇和水，得到SiO：溶胶浓缩液；然后与光固化树脂PEA、活性稀释剂 TPGDA及光引发剂Irgacule 其性能进行表征。结果表明，经过WD一20改性后的纳米Si0：在光固化树脂中具有良好的分散性和稳定性，同时涂 膜固化后的耐摩擦性等性能显著提高，拓宽了光固化树脂的应用范围。 关键词纳米Si0：溶胶；改性；uV固化，复合 中图分类号TQ320 文献标识码A 文章编号1674-5752(2012)02—46—05 of Resin andPerformanceUV-Curable Preparation Analysis Composite withModifiedNano．SiO， YU Wen-tao Guang—XUe，CHENQi—feng，HUANG Ming·guang，CHEN and China (State UniversityTechnology，Guangzhou510640，Ch／na) KeyLaboratoryofPulp PaperEngineering，South of AbstractInthis solwas the reactionofTEOSand thenthesurface using ethanol，and paper，Nano—Si02prepared hydrolysis was after solwasmodifiedthesilane WD-20．Theconcentrateof sol out of Si02 drying Si02 using couplingagent prepared the alcoholandwaterunder resinwithin was by remaining vacuum．Then，thecomposite light-curednano·Si02got mixing solwiththe resin diluentsTPGDAand 1173underultrasonic．Andthe PEA，reactive si02 light—cured photoinitiator地acure of resinwascharacterized and size results the