硅烷化处理对烧结钕铁硼永磁材料耐腐蚀性能的影响.doc.DOCVIP

硅烷化处理对烧结钕铁硼永磁材料耐腐 蚀性能的影响 张浩张鹏杰曹玉杰刘家琴衣晓飞陈静武吴玉 合肥工业大学工业与装备技术研宄院稀土永磁材料 家重点实验室（安徽大地熊新材料股份有限公司） 合大学材料科学与工g学院 采用环境友好的硅烷化处理技术在烧结钕铁硼磁体表面制备一层硅烷转化膜， 对烧结钕铁硼磁体进行暂时性防护。采用正交试验对过程中的工艺参数进行优 化。釆用冷场发射扫描电子显微镜（SEM）、拉力试验机、动电位极化曲线及中 性盐雾试验（NSS）对所制备的硅烷转化膜的形貌、膜/基体之间结合力以及耐腐 蚀性能进行研究。结果表明:硅烷转化膜均匀的涂覆在烧结Nd Fe B磁体表面，涂 层致密性高、无孔隙、裂纹等缺陷。硅烷转化膜与基体之间的膜/基结合力强度 可达14. 14 MPa。薄膜耐中性盐雾试验可达12 h,硅烷转化膜在W化过程中醇基 之间脱水缩合反应使硅烷转化膜表面形成只有不同交联密度的IX域，在Na C1 溶液中交联密度低的区域首先水解溶解是造成磁体表面硅烷转化膜腐蚀失效的 主要原因。 关键词： 烧结钕铁硼;永磁材料;硅烷转化膜;耐腐蚀性能;腐蚀机理; 基金：中国博?丄?后科学基金（2017M612065） Effect of silanization treatment on corrosion resistance of sintered NdFeB permanent magnets ZHANG Hao ZHANG Peng-jie CAO Yu-jie LIU Jia-qin YI Xiao-fei CHEN Jing-wu WU Yu_cheng Institute of Industry and Equipment Technology， Hefei University of Technology; School of Materials Science and Engineering， Hefei University of Technology; State Key Laboratory of Rare Earth Permanent Magnet Materials (Earth-Panda Advance Magnetic Material Co Ltd); Abstract： An environmental ly friendly silane conversion film was prepared on NdFeB substrate surface by silane technology to improve the corrosion resistance of the sintered NdFeB magnet. The parameters of deposition process were optimized by orthogonal experimental design. The morphology and bonding force between coating and substrate of the silane conversion film were studied by means of scanning electron microscopy ( SEM) and tensile testing machine. The corrosion resistance of the silane conversion film was studied by potcntiodynamic polarization curve test and neutral salt spray test ( NSS) . The results show that the silane conversion film is uniformly coated on the sintered NdFeB magnetic surface with high density, and no porosity and crack can be observed. The bonding force between the silane conversion film and substrate is up to 14. 14 MPa. The neutral salt spray test of the silane conversion film can reach 12 h. There are different crosslinking density area formed in the surface of the silane conversion film due to the