eu3和 sm3掺杂的 amoo4acasrba发光材料的word格式论文.docx

摘 要用高温固相法制备了 AMoO4 ?A ??Ca, Sr, Ba?、 AMoO4 : Eu3???A ??Ca, Sr, Ba?和 AMoO4: Sm3???A ??Ca, Sr, Ba?。XRD结果表明，在850℃空气气氛中灼烧5h 得到 了 白 钨 矿 结 构 的 AMoO4 ?A ??Ca, Sr, Ba??，而 AMoO4: Eu3???A ??Ca, Sr, Ba??和AMoO4: Sm3???A ??Ca, Sr, Ba?则均保持各自基质 AMoO?A ??Ca, Sr, Ba?的晶体结4构。另外，我们还对荧光粉的发光特性和发光机理进行了探究。AMoO4 ?A ??Ca, Sr?的发射光谱均表现为 400 ??740nm 之间的发射宽带，其形 状均可用一个Gauss峰拟合，但是 CaMoO4 的宽带发射比 SrMoO4 强得多。而用紫 外光激发 BaMoO4 ，未观察到可见光发射现象。 AMoO4 ?A ??Ca, Sr?的激发光谱均表现为 220 ??340nm 之间的激发宽带，其形状均可用两个Gauss峰拟合。在 AMoO4: Eu 3???A ??Ca, Sr?中，有两个 Eu 3??发光中心，其发射能量分别来源于 Eu 3???允 许 的 O ??Eu电 荷 迁 移 态 吸收 过程 和 基质 AMoO4?A ??Ca, Sr??的O ??Mo 电荷迁移态跃迁过程。然而，在 BaMoO4: Eu 3??中，只有一个 Eu 3??发光中64心，其发射能量来源于基质 BaMoO4 的 O ??Mo 电荷迁移态跃迁过程。3?在 AMoO4 ?A ??Ca, Sr, Ba?基质体系中， Sm的G5 2 ??H9 2 电偶极跃迁产生4强的鲜红色发射。 AMoO4: Sm3???A ??Ca, Sr, Ba?均在紫外波段有一个吸收宽带，其中，CaMoO4: Sm3???的宽带激发强度最大。Sm3??掺杂浓度小的 SrMoO: Sm3??和3?BaMoO4 : Sm在 近 紫 外 光 区404nm处 有 较 强 的 吸 收 。 在AMoO44: Sm3???A ??Ca, Sr, Ba?中，基质 AMoO?A ??Ca, Sr, Ba?发生 O ??Mo 电荷迁移态跃迁吸收紫外光，然后通过非辐射共振能量传递途径将能量传递给 Sm3??。关 键 词 ：AMoO4?A ??Ca, Sr, Ba??；AMoO4: Eu 3??A ??Ca, Sr, Ba??；3?AMoO4 : Sm?A ??Ca, Sr, Ba?；发光特性；能量传递AbstractAMoO4 (A=Ca, Sr, Ba), AMoO4:Eu3+ (A=Ca, Sr, Ba) and AMoO4:Sm3+ (A=Ca,Sr, Ba) were prepared by solid-reaction in air. X-ray powder diffraction (XRD) analysis confirmed the sheelite structure of AMoO4 (A=Ca, Sr, Ba) under 850℃ for 5h, respectively. And their luminescent properties and luminescence mechanismhave been investigated.AMoO4 (A=Ca, Sr) produces a broad emission band located between 400 nm and 740 nm under UV-light excitation, which can be fitted with one Gaussian peak. The emission intensity of CaMoO4 is much higher than that of SrMoO4. However, the phenomenon of visible light emission is not observed when BaMoO4 is excited by UV light. The excitation spectra of AMoO4 (A=Ca, Sr) is a broad band located between 220 nm and 340 nm, which can be fitted with two Gaussian peaks.There exist two Eu3+ luminescence centers in AMoO4:Eu3+ (A=Ca, Sr), whose emission energy comes from O-E