eu3掺杂的以y2o33sio2 y2o32tio2 y2o32tio23sio2为基质的红色荧光粉的结构与性质分析word格式论文.docx

优秀毕业论文 精品参考文献资料 ABSTRACT The red fluorescence powders that are prepared by activate materials doped with rare earth (RE) Eu3+ are becoming the main red light sources in the LED devices. In this paper, substrate with Y2O3-3SiO2, Y2O3-2TiO2 and Y2O3-2TiO2-3SiO2, one method is Sol-gel method and precipitation method are combine, another is Sol-gel method. The crystal structure and the luminescent properties of the samples are measured and characterized by using the method of DTA-TG, IR, XRD, TEM and excitation and emission spectra, respectively. The methods select same matrix materials are TEOS, N-butyl titanate, titania, yttrium nitrate, europium chloride. The sol-gel method and precipitation method are combine more than sol-gel method with add oxalic, the last a method preparation the sample material at the same annealing temperature is more likely to form crystals. Crystalline materials doped with rare earth ions, rare earth ions emit light luminous intensity and color from the emission spectral purity in favor; the use of sol - gel method of luminescent materials doped with rare earth ions between the matrix and the matrix uniform, favorable energy transfer, but compared to other method is not easy to form crystals. Material prepared Y2O3-3SiO2:Eu3+ by the sol-gel method annealed at 800℃, amorphous structure form in it, there are mainly non-bridging oxygen Si-O bond, Y2O3 morphology is nanoscale rod. Material of Y2O3-3SiO2:Eu3+ prepared by combining method, annealed at 800 ℃ ,which exist Y2O3 cubic phase, mainly exist Si-O-Si bridging oxygen bond, nanoscale Y2O3 is spherical morphology, The materials produced of two methods the best Eu doping were 6.0%, All of them show characteristic of Eu3+ emission peak at 613 nm, the optimal excitation peak in the ultraviolet region of 257nm and 395nm respectively; two materials prepared in the corresponding optimal excitation wavelength, the material prepared by the combining method color purity and luminous intensity is r