lasrfecoo3δgdceo2δ复合阴极材料及电化学性能研究-study on the composite cathode material and electrochemical properties of lasrfeco 3 δ gd ceo 2 δ.docxVIP
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lasrfecoo3δgdceo2δ复合阴极材料及电化学性能研究-study on the composite cathode material and electrochemical properties of lasrfeco 3 δ gd ceo 2 δ
AbstractSolid-oxidefuelcells(SOFCs)isconsideredasoneofthemostpromisingdevicesbyconvertingchemicalenergyintoelectricalenergy.However,theinterfacialpolarizationresistancesbetweenelectrolyteandelectrodesincreasedramaticallyastheoperatingtemperatureisreduced.Thus,thedevelopmentofnovelelectrodematerialsand/oruniquemicrostructuresisoneofthecriticalissuesinthedevelopmentofnewgenerationSOFCsoperatingat600-800°C.Inthisstudy,weinvestigatedthecompositecathodematerialLa0.6Sr0.4Fe0.8Co0.2O3-δ(LSFC)andGd0.2Ce0.8O2-δ(GDC)byin-situsol-gelmethod,andthephysicalandelectrochemicalpropertieswerecharacterized.Theporouscompsitecathodewithhoneycombstructurewassynthesizedbybreathfiguresmethod.Thecompositeelectrodewithsuchmicrostructurepossessestheadvantagesoffastgasdiffusionandextendedtriple-phaseboundaries(TPBs).WesynthesizedLSFC-GDCcompsitecathodematerialusingin-situmethod,andstudiedtheinfluenceofsynthesisconditionsonthepropertiesofthecompositematerial.TheX-raydiffraction(XRD)analysisshowedthattheLSFCandGDCweresuccessfullysynthesizedwithoutimpurities.Thegrainsizeofas-synthesizedLSFC-GDCcompositematerialwassmallerthanthegrainsizeofLSFCobtainedunderthesamesynthesisconditions.Eachphasewasmoreregularlydispersedinthecompositematerialthanthematerialpreparedbymachincialmixingmethod.TheTECofLSFC-GDCwaslowerthanLSFCandwasclosetotheTECofGDC,whichindiacatedthematerialwassuitablefortheSOFCcathode.Afterthecomprehensivecharacterizationofavarietyoftestingmethods,ultimatelythebestsynthesisconditionsofthecompositecathodematerialweredetermined:thebestadditionofGDCtoLSFCwas50mass%andtheoptimumcalciningtemperatureofthematerialwas900℃.Furthermor,thecalciningtemperatureandholdingtimewereinvestigated.EISwereadoptedtoexaminetheelectrochemicalperformanceofthecathodecalcinedatdifferenttemperatureandheldfordifferenttime.Theresultsshowedthatthebestcalciningtemperaturewas1000°Candthebestholdingtimewas2h.ThepolarizationresistancesoftheLSFC-GDCcompositecathodedisplaytheRpvaluesof0.17Ω·cm2at800°C,and0.33Ω·cm2at750°C.The
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