卟啉 酞菁及螺菁类金属配合物的合成与性质分析-synthesis and properties analysis of porphyrin phthalocyanines and spirocyanine metal complexes.docxVIP

pyrrole stretching, isoindole breathing, C–H bend and aza stretching are decreased sensitive to the rare earth ionic size, and remain basically unchanged along with the lanthanide contraction. These facts indicate that the π-π interactions in these mixed triple-deckers are weaker than those in the double-deckers. Novel heteroleptic double-decker rare earth complexes PcM(HcR8) (M = Pr, Nd, Sm, Eu) (R = OMe, OC8H17), metal free and transition metal complexes MHc(OC8H17)8 (M = HH, Fe, Co, Ni, Cu) have been synthesized. These complexes were characterized by IR, MS and UV-vis spectra. They have good solubility in common organic solvents. The electronic absorptions of MHc(OC8H17)8 (M = HH, Fe, Co, Ni, Cu) are obviously red shifted compared with the related phthalocyanin complexes. However the synthesis and purification of heteroleptic double-decker rare earth complexes PcM(HcR8) (M = Pr, Nd, Sm, Eu) (R = OMe, OC8H17) are more difficult than those in the related porphyrinato-phthalocyaninato complexes. KEY WORDS：Porphyrin, phthalocyanine, helicenocyanine, sandwich type, rare earth 目 录 HYPERLINK \l _bookmark0 第一章 文献综述1 HYPERLINK \l _bookmark1 1.1 卟啉酞菁化合物的研究进展1 HYPERLINK \l _bookmark2 1.1.1 卟啉酞菁化合物的概述1 HYPERLINK \l _bookmark3 1.1.2 卟啉酞菁化合物的应用领域4 HYPERLINK \l _bookmark4 1.2 三明治型卟啉酞菁稀土配合物的概述5 HYPERLINK \l _bookmark5 1.3 螺菁类化合物的概述6 HYPERLINK \l _bookmark6 第二章 三明治型三层卟啉酞菁稀土配合物的合成与谱学表征9 HYPERLINK \l _bookmark7 2.1 引言9 HYPERLINK \l _bookmark8 2.2 试剂及仪器10 HYPERLINK \l _bookmark9 2.2.1 试剂及规格10 HYPERLINK \l _bookmark10 2.2.2 主要仪器11 HYPERLINK \l _bookmark11 2.3 实验部分12 HYPERLINK \l _bookmark12 2.3.1 自由卟啉 H2TPyP 的合成 12 HYPERLINK \l _bookmark13 2.3.2 三明治型三层混杂卟啉酞菁稀土配合物的合成13 HYPERLINK \l _bookmark14 2.4 结果与讨论14 HYPERLINK \l _bookmark15 2.4.1 合成方法14 HYPERLINK \l _bookmark16 2.4.2 谱图分析15 HYPERLINK \l _bookmark17 2.5 小结23 HYPERLINK \l _bookmark18 第三章 混杂三明治型三层稀土配合物的拉曼光谱26 HYPERLINK \l _bookmark19 3.1 引言26 HYPERLINK \l _bookmark20 3.2 实验部分26 HYPERLINK \l