不同形貌硫化铋纳米材料的制备分析-preparation and analysis of bismuth sulfide nanomaterials with different morphologies.docxVIP

Abstract In this paper, Bi2S3 nanomaterials with different morphologies were synthesized by microwave irradiation, fluxing, solvothermal method and hydrothermal method. The products were characterized by SEM, TEM, HRTEM, XRD and UV-Vis. This main content includes four parts: synthesis of Bi2S3 nano-flowers by docomposing single-source precursor under microwave irradiation; preparation of Bi2S3 nanoflowers by hydrothermal method; synthesis of Bi2S3 nanorods at the interface of two immiscible liquids; preparation of Bi2S3 nanoflowers by fluxing single-source precursor method. Bismuth trisulfide (Bi2S3) nanomaterials with flowers-like morphologies have been successfully synthesized by microwave irradiation method, using Bi(S2CNEt2)3 as raw materials and ethylene glycol as solvent. X-ray diffraction (XRD) indicates that the obtained sample is orthorhombic phase with calculated lattice parameters a=0.4011 nm, b=1.114 nm, and c=1.136 nm. Scanning electron microscopy (SEM) and transmission electron microscope (TEM) images show that Bi2S3 is flower-like morphology, and each flower-like structure composed of nanorods with diameters ranging from 80 to 135 nm and with length ranging from 0.9 μm to 1.5 μm. UV-Vis analysis indicates that the band gap of Bi2S3 nanoflowers is 1.72 eV. Radiation time, solvent and surfactant have influence on the morphologies of the products. Bismuth sulfide nano-flowers have been prepared by hydrothermal method, using bismuth chloride and sodium thiosulphate as source materials, poly(vinyl alcohol)-124 as a capping reagent. X-ray diffraction indicates that as-prepared product is orthorhombic-phase Bi2S3 with calculated lattice parameters a=0.3982 nm, b=1.113 nm, c=1.132 nm. Scanning electron microscopy image (SEM) shows that the flower-like Bi2S3 is composed of nano-sheets with 5080 nm in thick. The observations of TEM and HRTEM also confirmed the result. In addition, the effects of time, temperature and different dosage of poly(vinyl alcohol)-124