生物质热解多联产过程机理及实验分析-mechanism and experimental analysis of biomass pyrolysis polygeneration process.docx

在处理量达100kg/h的生物质热解移动床中试试验装置上进行了移动床热解试验研究，结果表明，采用大长径比移动床热解管以及高温烟气冲刷换热的方式可以有效缩短生物质热解所需时间，能够将生物质的热解温度提升至600°C，稳定运行时，生物质从上至下在具有稳定温度范围的区段内依次经历干燥脱水、吸热升温、放热热解及焦炭吸热升温等过程；气体产物中H2、CH4、CO、CO2分别达10%、15%、30%和45%，热值可达11MJ/m3，液体产物中，乙酸含量下降，糠醛、愈创木酚、领苯二酚的含量都超过了5%，在富集度上有所提高；焦炭产品热值达到32MJ/kg；热解移动床转化一吨生物质所需能耗为2500-2750MJ。关键词：热解多联产、生物质、热解产物、焦炭结构、移动床热解AbstractThepyrolysisisaimportantmethodinthesehermalcovertiontechnology,whichcangenerateavarietyofvaluableproductsfromthethermaldecompositionoflignocellulosicbiomassmacromer.Currently,thepyrolysistechnologiescontainthepyrolysiscarbonization,thepyrolysisliquefactionandpyrolysisgasificationtechnology.Thesetechnologieaareusedtoobtainthemaximumyieldandofasingleproductandonlyconcernabouttheoptimaluseofthesingleproduct,buttheotherproductsduringtheseconversionprocessesarelackoffsufficientattention.Underthisbackground,theStateKeyLaboratoryofcoalcombustiondevelopedanovelbiomasspyrolysispolygenerationtechnologywhichcanobtainseveralvaluableproductsduringacontroledpyrolysisprocess.Thisthesisisusedtoreportthemechanismandapplicationresearchaboutthebiomasspyrolysispolygenerationtechnology.Atfirst,aTG-FTIRanalysiswasusedtorevealthepyrolysisandgasreleasecharacteristicsof5differenttypesofbiomassfeedstock,andthekineticsmodelofpyrolysisandgasreleasewerebuiltbasedonthetheGaussianfittingofthree-componentpyrolysismodel.Theresultsshownthatthemainpyrolysiszonewasfrom190to400oCfortheserawmaterials.Andtherewasapositiverelationshipbetweenthemaximumrateofweightloss(DTGmax)andthedry-basedvolatilecontent(Vdb)whileanegativecorrelationwaspresentwithdry-basedashcontent(Adb).Agoodsimulationofbiomasspyrolysischaracteristicswasobtainedbythethree-componentpyrolysismodel.Thetotalpyrolysisreactionactivationenergyofcottonstalk,raperod,tobaccostem,ricehuskandbambooare132,122.85,81.87,123.89and123.44KJ/mol,respectively.Thepyrolysispolygenerationexperimentintherangeof250°Cto950°Cfor5typesofrawmaterialswasconductedonaisothermalfixedbedinalaboratoryscale,whiletheproductdistributioncharact