石墨烯硫复合正极材料的制备和性能分析-preparation and performance analysis of graphene-sulfur composite anode material.docxVIP

AbstractThelithium–sulfur(Li-S)batteryhasbeenrecognizedasapromisinghighefficiencylithium-ionbatterybecauseofitshightheoreticalspecificcapacityandenergydensities,lowcostandtoxicity.However,thelowerconductivityofsulfurandthedissolutionofpolysulfide,generatedduringthedischargeprocess,inorganicelectrolytehavebadinfluenceoncyclestabilityofthecell.Graphene,aone-atomlayerofgraphite,possessesauniquetwo-dimensional(2D)structure,highconductivityandchargecarriermobility,hugespecificsurfacearea,greatmechanicalstrengthandlowdensity,hasshowedgreatpotentialandprospectintheareaofcathodematerialofLi-Sbattery.Thispaperdesignsseveralgraphen/sulfurcompositeswithhighsulfurcontentascathodeinlithium-ionbattery.ThemorphologyandstructureofcompositeswerecharacterizedbyFT-IR,XRD,SEMandTG,andthecyclestabilitywascharacterizedbycharginganddischargingatconstantcurrent.Thenwetheconnectionbetweenthestructureandspecificcapacity,cyclestabilityhasbeenresearched.Wepreparedintercalatedstructuregraphene/sulfur(HRGO/S)compositewithsulfurcontentashighas77.8%viaameltingmethod.Thefirstcyclecapacityofcompositeswas660mAh/gat0.1C,butfadto425mAh/gover50cycles.Theconservationrateofcyclecapacityjustwas61.7%.Thequickdecreaseincapacityismainlyduetononfullyenclosedstructurewhichleadstoquickactivemasslossfrompolysulfidedissolution.Wepreparedsubmicronsulfurenvelopedbygrapheme(S@RGO)particleswithsulfurcontentashighas83.9%inalkalineGOaqueous.Thefirstcyclecapacityofcompositeswas653mAh/gat0.1Candfadto535mAh/gover50cycles.Andtheconservationrateofcyclecapacitywasincreasedto81.9%.Thetotallyencapsulatedstructurebygraphenehadimposerestrictionsonthedissolutionanddiffusionoflong-chainpolysulfide.WefirstpreparedstablesulfurparticlescoatedwithpolymerwiththehelpofsurfactantandthenencapsulatedbygraphenetoobtainS@PEG@RGOcompositeswithsulfurcontentashighas77.8%.ThefirstcyclecapacityofcompositeswasII546mAh/gat0.1Cbutonlyfadto516mAh/gover50cycles,andtheconservationrateofcyclecapacitywasincreasedto94.5%at0.1C.Evenmore,itkept88.5%(508mAh/g