微纳米材料硫化锌铜的制备及可见光光催化性能分析-preparation of micro-nano material zncu and analysis of visible light photocatalytic performance.docxVIP

AbstractInthispaper,CuxZn1-xSmicro/nanomaterialswithdifferentmorphologiessuchasmicrospheres,microtubes,flower-likemicrospheres,wereobtainedbyhydrothermalandsolvothermalmethod.Thephotocatalyticactivityofthesampleswereinvestigated.UsingCuCl2·2H2O,ZnSO4·7H2OandCH3CSNH2asrawmaterials,CuxZn1-xSmicrospheresweresynthesizedbyhydrothermalmethod.Thecrystalstructures,morphologiesandopticalpropertiesofthesampleswerecharacterizedbyXRD,SEM,FT-IRandUV-Vis,andtheirphotocatalyticactivitywasstudied.TheresultsshowthattheCuxZn1-xSmicrosphereshavethesamecrystalstructureofcubicphaseZnS,andthecrystalsizeofthesamplesgraduallydecreaseswiththeincreaseofmolarratiox.Thereactiontemperature,reactiontime,differentmolarratiocoppertozinc,surfactantsanddifferentcopperandzincsaltshaveagreatimpactonmorphologyofthesamples.FT-IRanalysisshowsthatCu0.03Zn0.97Sisstabble,andnooxideisproducedowingtoitsoxidation.Ithasagoodtransmittanceoftheinfraredlight.UV-VisanalysisshowsthattheCuxZn1-xSmicrosphereshavestrongabsorptionintheultravioletregion,however,theabsorptioninvisibleregionenhancedwiththecopperandzincmolarratioxincreasing.PhotocatalyticdegradationofrhodamineBrevealsthatthesampleswithdifferentcopperandzincmolarratiohavedifferentphotocatalyticeffect,andthephotocatalyticactivityenhancedwiththecopperandzincmolarratioxincreasing.UsingCuCl2·2H2O,ZnSO4·7H2OandCH3CSNH2asrawmaterials,CuxZn1-xSmicrotubeswerepreparedbyhydrothermalmethod.ThesampleswerecharacterizedbyXRD、SEM、TEMandUV-Vistechniques,andtheirphotocatalyticactivitywasstudied.TheresultsshowthatmostofdiffractionpeaksofCuxZn1-xScoincidewithhexagonalphaseCuS,anditscellparametersarea=0.3796nm,c=1.6380nm.Theeffectsofdifferentconditionssuchasthemolarratiocoppertozinc,reactiontemperatureandreactiontimeonmorphologyofthesampleswerestudied.TEManalysisshowsthatCu0.8Zn0.2Smicrotubesarecomposedofthenanoflakewithabout35nminwidth,andabout80nminlength.UV-VisanalysisshowsthatCuxZn1-xShavedifferentdegreesofabsorptionintheultravioletandvisibleregion,andCu0.8Zn0.2Shasabroadab