无铅钽铌酸钾锂晶体的介电和压电性能分析-dielectric and piezoelectric properties of lead-free potassium lithium tantalum niobate crystals.docx

的电滞回线进行表征，得到其矫顽场和剩余极化强度，分析其变化规律和原因。结合热释电和电滞回线的测试结果对KLTN晶体的自发极化特性进行机理分析。对无铅晶体KLTN各种振动模式下的压电性能进行系统地研究。制作富铌KLTN晶体横向长度振动模式、厚度振动模式、纵向振动模式以及横向切变模式的压电振子，给出和分析相关的压电、机电耦合和弹性性能参数，并与传统的压电材料进行对比；利用超高频振动计，分析其谐振行为，得到谐振频率下三维微观形貌。对无铅晶体KLTN各项性能的晶向依赖特性进行计算和模拟，绘制其三维分布图。关键词：无铅晶体KLTN；晶体生长；介电行为；热释电和铁电性质；压电性能和晶向依赖特性AbstractWiththegrowingdevelopmentofscienceandtechnology,asabasicindustryforthedevelopmentofhumansociety,materialscienceshouldkeepabreastofthetimes.Aslarge-scaleapplicationcurrentlyislead-zirconium-titanate,piezoelectricmaterialisamajorconcerninrecentyears;fortheenvironmentandsustainabledevelopment,lookingforlead-freepiezoelectricferroelectricmaterialstoreplaceitiscontemporaryandhistoricalmissionoftheresearchersintherelatedfield.Inthepasttenyears,therearemassexploitationsoflead-freepiezoelectricceramicsandtheirmodificationintheareaofinternationalferroelectric,butreplacingthelead-zirconate-titanateceramicstoapplicationistooearly;thus,theemphasisfocusonhowtofurtherimprovetheperformanceandstabilityoflead-freematerials.Duetoitshighorientation,theperformanceofferroelectricsinglecrystalsisfarbeyondthatofthesamecompositionofceramics;moreover,thestructureofferroelectricsinglecrystalissimplerthanthatofceramic,aswellasconvenienttoresearchonorientation-dependentphysicalmechanism.Potassiumtantalumniobatecrystalisawell-knownsolidsolutioninphotorefractivematerial,thevastmajorityofresearchisfocusedontheopticalproperties;however,systemicelectricalproperties(dielectric,pyroelectric,piezoelectricandferroelectricproperties)arerarelyreported.Anduntilnow,researchhasfocusedonthetantalum-richpotassiumtantalumniobatecrystal;niobium-richregionshavenotbeenstudied.Thus,combiningthedevelopmentbackgroundoflead-freepiezoelectricandferroelectricmaterialandresearchstatusofpotassiumtantalateniobatecrystal,andthroughanalysissynthesisandcompositionalphasediagramofpotassiumtantalumniobatecrystal,aseriesofbigsized,highquality,andniobium-richlithium-dopedofpotassiumtantalumniobatecrystals(potassiumlithiumtantalumnio