TiO2纳米棒阵列的制备、性质及在染料敏化太阳能电池中的应用分析-凝聚态物理专业论文.docxVIP

重庆大学硕士学位 重庆大学硕士学位论文 英文摘要 PAGE PAGE VI ABSTRACT TiO2 has become the research hotspot due to its rich resources, security, non-toxic, stable chemical properties. One-dimensional (1-D) TiO2 including nanorod and nanowire have attracted much attention since TiO2 nanowire/nanorod have good surface roughness and photoelectric property. So TiO2 nanowire/nanorod have a wide range of applications in many ways，such as self-cleaning, antifouling, hydrophobicity, inhibiting the surface corrosion and dye-sensitized solar cells (DSSCs). So it is necessary to carray on the systematic study. In this paper, on one hand, TiO2 nanorod arrays (NRAs) with tunable surface morphologies were prepared in different HCl concentration solutions by hydrothermal method on fluorine-doped tin oxide coated glass substrates. The properties of these nanostructures were characterized by XRD, SEM and XPS. TiO2 NRAs exhibit a high water contact angle (WCA) after hydrophobic treatment. Baded on the results, we analyzed the factors of HCl concentration and hydrophobic agents which influence the hydrophobic performance of TiO2 NRAs. On the other hand, high orientation of TiO2 NRAs were prepared on seeded substrate by combination of sol-gel and hydrothermal synthesis method and the properties of these nanostructures were characterized by XRD, SEM and ultraviolet-visible spectrophotometer. The affect of seed layers on the structure, morphology and dye adsorption amount of TiO2 NRAs were studied. The properties of the DSSCs based on TiO2 NRAs with and without seed layers were investigated by current-voltage characteristics. In addition, we studied the effect of seed layer on the the performance of dye-sensitized solar cells. The main results are as following: ①Rutile TiO2 NRAs were prepared in different HCl concentration solution by hydrothermal method on FTO substrate and characterized by XRD, SEM and XPS. We analyzed the influence of HCl concentration on the morphology and roughness of TiO2 NR