TiO2纳米管同轴异质结阵列在光催化及锂硫电池方面的应用研究-材料学专业论文.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II万方数据 II 万方数据 Abstract As an important wide-gap semiconductor, TiO2 is widely used in photocatalytic water splitting, toxic pollutants degradation, solar cell, air purification, self-cleaning glass, et al. in the paper, TiO2 nanotubes are used in the field of photocatalytic hydrogen production and lithium-sulfur battery cathode materials. The fabrication and characterization of CdSe/CdS/TiO2 nanotube-array coaxial heterogeneous structure that has potential applications in photocatalytic water splitting and toxic pollutants degradation are investigated. CdSe(top)/CdS(under) double-layer is conformally deposited onto TiO2 nanotubes by SILAR and ECALD, respectively, for the CdS under layer and the CdSe top layer. Such double sensitized TiO2 nanotubular photoelectrode exhibits significant enhancements in photoconversion efficiency, visible light response, and efficient hydrogen generation. The detailed preparation process and the surface morphology, phase structure, elemental analysis, and photoelectrochemical properties of the resulting films with the CdSe/CdS/TiO2 nanotube-array coaxial heterogeneous structure are discussed. The photoconversion efficiency of 9.47% and hydrogen generation rate of 10.24 ml/(h·cm2) were observed. Both values are a 7-fold enhancement compared with that of the pure TiO2 nanotube. The as-prepared photoelectrode presents potential application for industrialized photocatalytic hydrogen generation in the future. In the paper, TiO2 nanotube arrays are also used as the base materials for the cathode materials of lithium-sulfur batteries. Polypyrrole (PPy) is polymerized into TiO2 NTs by electrochemical polymerization method and sulfur nano-particles are deposited by electrochemical deposition method, which results in the formation of coaxial heterostructures. XRD, FESEM, EDAX, TEM，LSV, CV, UV-vis are tested to analysis phase, morphology, elemental distribution of PPy(S)/TiO2 NTs. The prepa