T101急冷塔腐蚀机制及防腐对策化学工程与技术专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II - 排液；塔盘与支撑架绝缘处理。依据塔的耐腐蚀材料的优选，建议 T101 采用 双塔体结构。进料口以上材质采用 16MnDR 钢，以下材质采用双相不锈钢， 上下塔体采用绝缘法兰连接，或整体材料采用 16MnDR 钢衬双相不锈钢复合 钢。并展望了其它的防腐措施，以待进一步研究。 关键词：腐蚀与防护；腐蚀机制；低合金钢；双相不锈钢；选材；耐蚀性 - - III - Abstract T101 quench tower plays an important role in the production of 3-chloride. its run condition can directly impact on whether the entire device can be able to operate normally and continually, and T101 quench tower corrosion protection guarantees that Industrialized large-scale production can get the best value In this paper, through the use of electrochemical tests, hanging experiments, XRD 、XPS and metallographic microscope methods , the corrosion reasons of the tower was anylised, the corrosion environment was simulationed in the laboratory , and the corrosion mechanism of the tower was studied. Then, some suggestions of practical corrosion protection was studied. the low-alloy steel 09MnDR, duplex stainless steel S2205, super duplex stainless steel S2507 was selected to carry out laboratory research for the corrosion resistance of the material characterization data, and further study of material corrosion mechanism in a simulated corrosion，and the applicate feasibility of the selected materials was discussed in the production field. There are three most important reasons of tower corrosion. First, excessive amount of water in the tower results that HCl dissolve in and form hydrochloric acid in the middle of tower.water was delivered into the tower by materiel and wash of the tower. Secondly, the tray floor and support bracket use different metals, constitute a galvanic corrosion. Third, anti-corrosion construction quality rejects. Compared 16MnDR corrosion behavior in HCL and simulation liquid(glycerol and a mixture of hydrochloric acid), glycerol: 10% hydrochloric acid = 88:12 was determined close to the corrosive solution in the tower; further studied the tower corrosion mechanism, through the polarization curve test and hanging e