TiC+TiB增强高温钛合金基复合材料的组织和性能研究-材料加工工程专业论文.docxVIP

哈尔 哈尔滨工业大学工学硕士学位论文 II II Abstract Melting-casting process in situ autogenous technique was adopted to prepare the TMCs with the matrix of Ti-5.5Al-4Sn-4Zr-0.3Mo-1Nb-0.5Si and reinforcement of TiC+TiB. The contents of reinforcement in the three titanium matrix composites were 9vol%TiC+1vol%TiB, 7vol%TiC+3vol%TiB and 5vol%TiC+5vol%TiB respectively . In addition, different heat treatment processes for each material were conducted. Then the microstructure and properties of as-cast materials as well as the materials after heat treatment were analyzed and tested. It is shown that the two reinforcements distribute along the grain boundary. Most of the TiC is granular or equiaxial, but the shape of TiB are needle or fibrous. The two reinforcements which are added simultaneously incline to grow mutually and to suppress the growing of each other. In the final titanium matrix composites, the size of reinforcements is relatively small. The introduction of TiC+TiB also plays a role of refinement on the matrix in a certain extent. After the heat treatment, no change takes place in the microstructure of TiB almost, and the microstructure is stable in high temperature. However, the microstructure of TiC has changed obviously. Meanwhile, these changes have the same tendency in composites with different contents of reinforcements: strip microstructures of TiC are molten and granulated, and TiC particles are gradually dissolved, whereas this tendency for TiC particles near to TiB is less a lot. In the whole process of heat treatment, TiB plays a certain restraining role to the solution of TiC. The compressive strength of casting Ti-based composites is obviously higher than the matrix of titanium alloy. The composite with reinforcements whose content is 5vol%TiC+5vol%TiB has the maximum increasing degree, and its compressive strength increases to 1699.26MPa, but the plasticity descends substantially. After the heat treatment, this phenomenon is obviously developed. The plasticity incre