TiO2类光催化剂的改性研究-化学工艺专业论文.docxVIP

improve interfacial charge transfer, enhance visible-light adsorption and provide plentiful phtotocatalytic reaction active sites. Finally, we investigated the effect of N doped titania-based photocatalysts. The N-TiO2 photocatalysts were prepared by high-temperature roasting, plasma processing, impregnation method, mechanical trituration and hydrothermal processing. It was found that the catalyst prepared by impregnation method showed the best photocatalytic activity in all kinds of N doped TiO2 photocatalsts. Meanwhile, N, GR, CuO co-doped P25 photacatalysts also showed much higher photocatalytic activity than TiO2-GR and CuO/TiO2-GR, as the doption of N can further enhance the ability of graphene for transmitting and transferring electrons. KEYWORDS：TiO2, graphene, CuO, N-doped, photocatalytic hydrogen evolution 目 录 第一章 文献综述 HYPERLINK \l _bookmark0 1 HYPERLINK \l _bookmark1 1.1 前言1 HYPERLINK \l _bookmark2 1.2 光催化水解制氢催化剂2 HYPERLINK \l _bookmark3 1.2.1 光催化机理及对光催化剂的要求 2 HYPERLINK \l _bookmark4 1.2.2 光催化水分解制氢催化系统的评价 4 HYPERLINK \l _bookmark5 1.2.3 提高光催化剂可见光响应的改性方法 4 HYPERLINK \l _bookmark6 1.2.4 光催化剂种类 7 HYPERLINK \l _bookmark7 1.3 TiO2 光催化剂 10 HYPERLINK \l _bookmark8 1.3.1 TiO2 基本性质 10 HYPERLINK \l _bookmark9 1.3.2 TiO2 光催化作用机理 11 HYPERLINK \l _bookmark10 1.3.3 提高 TiO2 光催化剂活性的主要方法 11 HYPERLINK \l _bookmark11 1.4 石墨烯类光催化剂概述15 HYPERLINK \l _bookmark12 1.4.1 石墨烯性质 15 HYPERLINK \l _bookmark13 1.4.2 石墨烯的制备方法 15 HYPERLINK \l _bookmark14 1.4.3 石墨烯为基础的复合光催化剂 16 HYPERLINK \l _bookmark15 1.5 论文研究的目的和内容21 HYPERLINK \l _bookmark16 第二章 实验部分 23 HYPERLINK \l _bookmark17 2.1 实验试剂、仪器及流程23 HYPERLINK \l _bookmark18 2.1.1 实验试剂 23 HYPERLINK \l _bookmark19 2.1.2 实验仪器 24 HYPERLINK \l _bookmark20 2.1.3 实验流程 24 HYPERLINK \l _bookmark21 2.2 催化剂制备过程25 HYPERLINK \l _bookmark22 2.2.1 光催化剂 CuO/TiO2 的制备 25 HYPERLINK \l _bookmark23 2.2.2 氧化石墨烯的制备 25 HYPERLINK \l _bookmark24 2.2.3 TiO2-GR 和 CuO/TiO2-GR 复合光催化剂的制备 26 HYPERLINK \l _bookmark25 2.2.4 N