β稳定元素对医用钛合金腐蚀性能的影响-材料物理与化学专业论文.docxVIP

II II Abstract Mo, Nb, Ta, Zr elements are β phase stablizers and good biocompabitable. By adding Mo, Nb, Ta, Zr, Sn elements to Ti, we can design new biomedical Ti alloys with good compatibility and low elastic modulus. In this thesis, Ti-Nb, Ti-Ta, Ti-Zr, Ti-Mo, Ti-Sn binary alloys and Ti-Nb-Sn and Ti-Ta-Sn ternary alloys with different Sn contents were prepared by vaccume arc melting furnace，and their microstructures were characterized by X-ray diffraction(XRD) analysis.The corrosion behaviors of these these alloys were investigated by electrochemical method. The effects of Sn contents and heat treatment on the microstructure and corrosion behavior were studied. The results indicated that Ti-15Mo, Ti-15Nb, Ti-15Zr, Ti-15Ta alloys have similar polarization curves, which showed a wide passive zone with a low passive electricity density. It implies that these alloys have high corrosion resistance. While, the over passive phenomenon and a high passive electricity density were observed in the Ti-15Sn alloy, implying that the alloy had poor corrosion resistance. Sn content has important influence on the mirostructure and the corrosion behavior. With the increase of Sn content, the self corrosion potential of Ti-Nb-Sn increased, implying the addition of Sn decreased the corrosion tendency of the alloy. But the addition of Sn increased the passive electricity density of the alloy, resulting in its passive film unstable. In constract, Sn had a little influence on the mircotructure and corrosion behavior of Ti-Ta-Sn alloys, and it slightly increase the stability of the passive film of Ti-Ta-Sn alloys. Heat treatment has an important influence on corrosion behavior of Ti-Nb-Sn and Ti-Ta-Sn alloys. The corrosion behaviors of these two alloys are not only dependent on the heat treatment but also on the compositions. It was found that, by annealing at 500?C, the corrosion behaviors of Ti-15Ta-3Sn, Ti-15Nb-5Sn, Ti-15Nb-3Sn had been improved. After annealed at 400?C, Ti-15Nb-5Sn