紫外高铁酸盐处理有机磷农药废水的实验分析-experimental analysis on treatment of organophosphorus pesticide wastewater by ultraviolet ferrate.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Organophosphorus pesticide wastewater is an important part of phosphorus pollution and environmental hazards, and Organic phosphorus pesticide is worldwidely used. Once flow into the environment, it leads to eutrophication which destroys the ecological balance on the one hand, and Pesticides Residue in crops accumulates in the body on the other hand, making human tissues damage. Organic phosphorus pesticide molecules cover a wide range of different characteristics, and an approach has not yet been found that can be universally applicable and effective. Biological treatment is of used through developing special bacteria, but Chemical methods are used more widely, including Fenton, TiO2 photo-catalytic method and Ozone Oxidation, et al. Since ferrate is a new found efficient and environment-friendly oxidant, it has high values in application and research whether used alone or in combination with other technologies, resulting from the much more stronger oxidizability of Fe(VI) and derived Fe(V), Fe(IV) than Fenton, ozone, KMnO4 and ClO4-. This article chooses two representative organic phosphorus pesticides, profenofos and glyphosate, to study the treatment effects by UV/FeO42- system, and their mechanisms. Ferrate was prepared by Direct Electrochemical Method in, and the optimum parameters of were found, viz. the optimal concentration of NaOH is 14~16M, and through accessing the current of 0.15A/cm2~0.2A/cm2 for 2~4h under 25~30℃, approximately 35mmol/L of ferrate could be stably obtained. The oxidant gained a significant removal rate on the substrate combining with the co-catalyst of UV, which promoted deriving Fe(V) and Fe(IV)from Fe(VI), resulting its oxidation greatly enhanced at the optimum pH9.0. 62.36% of profenofos was removed when Cprofenofos=10.0 mg/L, and CFe(VI) ： =250 μmol/L, along with 82.05% orthophosphate were claimed by dosing 300 μmol/L into the 5.0 mg/L of glyphosate(aq). The CODC