环硅氮烷的合成与应用研究进展-上海有机化学研究所.PDF

2011 年第 31 卷 有 机 化 学 Vol. 31, 2011 第 6 期, 932～945 Chinese Journal of Organic Chemistry No. 6, 932～945 ·学术动态· 环硅氮烷的合成与应用研究进展(1)——环二硅氮烷 滕雅娣* 孙驰宇 盛永刚 王淑丽 (沈阳化工大学应用化学学院 沈阳 110142) 摘要 环二硅氮烷是有机硅氮化合物中结构与性能比较特殊的一类化合物, 在材料化学及配位化学领域有重要的潜在 应用前景. 综述了近年来环二硅氮烷的合成方法与应用研究进展. 在合成方面, 主要分为 3 条路线, 分别由环三硅氮烷 锂盐、取代硅胺及六氯化二硅为起始物. 在应用领域, 介绍了环二硅氮烷的离子开环聚合、等离子聚合、与其它单体 的共聚、水解和金属配合物的制备及其在陶瓷、粘合剂和预想的催化剂上的应用. 关键词 环二硅氮烷; 离子开环聚合; 金属配合物; 陶瓷前驱体 Progress in Synthesis and Application of Cyclosilazanes (1)— Cyclodisilazanes Teng, Yadi* Sun, Chiyu Sheng, Yonggang Wang, Shuli (College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142) Abstract Cyclodisilazanes are of great pecularity for their configuration and property in organosilicon compounds, and have markedly potential prospect of application in materials chemistry and coordination chemistry. The progress in synthesis and application of cyclodisilazanes in recent years is reviewed. Three methods of synthesis which made from lithiated cyclotrisilizane, aminosilane and disilicon hexachloride are described. The productions of cyclodisilazanes received by ion ring-opening polymerization, plasma polymerization, copolymerization, hydrolysis and metal coordination, and their applications in ceramic, adhesives and expected catalysts are exhibited. Keywords cyclodisilazanes; ion ring-opening polymerization; metal complex; ceramic precursor 由交替 Si—N 键形成的四元环硅氮烷最早于 1953