超声辅助浸渍法制备γ-Al2O3负载铜锰基吸附剂及其脱硫性能的分析-化学工艺专业论文.docxVIP

太原理 大学硕士研究生学位论文 PREPARATION OF Mn-Cu-BASED SORBENTS LOADED ON y-Ah03 BY 1岛1PREGNATION ULTRASOUND-ASSISTED AND THEIR DESULFURIZATION PERFORMANCE ABSTRACT Coal pol y-generation technology，in which the synthesis gas is produced by the gasified coal gas and pyrolyzed coaJ gas，can not only realize the reasonabJ e step uti l ization of raw mateI臼1 and energy，but also improve greatly the comprehensive utilization efficiency of the system. This is the inevitabl e trend for the efficiency and clean utilization of coal resources. The desulfurization from coal gas under medium temperature is a key process in this technology. To solve the problems of low desulfu rization efficiency，bad thermal stabi lity，hard regeneration ，and so on，the research for a new method used to prepare a recyclable sorbent with h igh sulfur capacity，high thermal stabil ity has important theoretical signi ficance and practical value. Ultrason i c wave can gcncrate h ole and smaJl bubbles inside liqu id th rough the cavitation effect. Th e h i gh temperature ，high pressUJ飞 strong shock wave and micro jet are produces during the processes of vibration ，expansi on， compression and collapse of the bubbles ，which is a kind special energy and hard to reali ze under the general conditions. The introduction of ultrasound for the pl叩aration of SOI机nts wi l l change the physica J and chemical propel1ies of sorbents，thereby improving th eir desulfurization ability. Selecti n g γ-Ab03 as 111 3 太原理工大学 币 1+研究生学衍，论文 the carrier，the properties and desulfurization abilities of the copper and manganese-based sorbents prepared by ultrasonic-assisstant impregnation method and conventional impregnation mcthod were studied in this topic . Compares the differences of sorbents prepared by these two rnethods，the results obtained are shown as folJows: The sorbent prepared by ultrasonic -assisstant impregnation method ha s the higher preci sion of desuJfuriz