层状复合陶瓷的制备与机械性能研究-材料加工工程专业论文.docxVIP

Classified Index: TQ174 U.D.C: 621.762.11 Dissertation for the Degree Of M.Eng. THE RESEARCH ON THE PRODUCING AND MECHANICAL CHARACTER OF LAMINATED CIRAMIC Candidate： Ren Qingwu Supervisor： Associate Prof. Wang Guofeng Academic Degree Applied for： Master of Engineering Speciality： Materials processing Engineering Affiliation: School of Mechatronics Engineering Date of Oral Defense: June,2009 Degree Conferring Institution: Harbin Institute of Technology 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - I - 摘 要 陶瓷基层状复合材料是一类受珍珠云母、贝壳等层状结构的启发而发展 起来的强韧化陶瓷，由于增韧效果显著，成为当前陶瓷材料研究的热点。本 文采用真空热压烧结法分别制备了 Al2O3-Si3N4/ZrO2-Al2O3 以及 ZrO2- Al2O3/Nb两种陶瓷基层状复合材料，系统研究了Al2O3-Si3N4/ZrO2-Al2O3 以 及ZrO2-Al2O3/Nb陶瓷基层状复合材料制备工艺、组织、性能之间的关系。 本文采用用真空热压烧结的方法制备出Al2O3-Si3N4/ZrO2-Al2O3 层状复 合陶瓷块体，经过力学性能测试和显微组织分析，得出在温度为 1550℃， 压力为 30MPa条件下，制备出的Al2O3-Si3N4/ZrO2-Al2O3 块体材料综合性能 最好。此时密度为 4.28g/cm3，致密度达到 96%。Al2O3-Si3N4/ZrO2-Al2O3层 状复合陶瓷表现出良好的力学性能，热压烧结试样的弯曲强度为 184MPa， 断裂韧性最高可达 5.2MPa? m1/2 ，Al2O3-Si3N4 层和ZrO2-Al2O3 层的维氏硬 度值分别为 16.95GPa，11.31GPa。分析了Al2O3-Si3N4/ZrO2-Al2O3 层状复合 陶瓷的三种增韧机制：裂纹偏转机制、纳米颗粒增韧、残余应力增韧。 本文采用热压烧结的方法制备出ZrO2-Al2O3/Nb层状复合陶瓷块体，经 过力学性能测试和显微组织分析，得出温度为 1550℃，压力为 30MPa时， 综合性能最好。弯曲强度达到 245MPa，断裂韧性达到 7.2 MPa? m1/2 。 Al2O3-ZrO2 层和 Nb 层维氏硬度值在 1500 ℃时最高分别为 8.12GPa ， 6.36 GPa。分析了ZrO2-Al2O3/Nb层状复合陶瓷的三种裂纹扩展方式。 关键词 Al2O3-Si3N4/ZrO2-Al2O3 层状陶瓷；ZrO2-Al2O3/Nb层状陶瓷；热压 烧结；显微组织 - - II - Abstract Laminated ceramic is a kind of high strength, high toughness creamics developed from pearl and shell. Due to its remakable toughen effect, laminated ceramic become a hotspot in current days. In this paper, Al2O3-Si3N4/ZrO2-Al2O3 and ZrO2-Al2O3/Nb laminated ceramic was fabricated by tape casting and hot press sintering. The lelationship of the process, microstructure and mechanical property of the Al2O3-Si3N4/ZrO2-Al2O3 and ZrO2-Al2O3/Nb laminated creamics were researched. This paper used hot press sintering to fabricate Al2O3-Si3N4/ZrO2-Al2O3 laminated ceramics. When the sintering temperature is 1550℃, the pressure is 30MPa by hot-press