反应性磷氮类和硅类阻燃剂的合成及真丝上的应用-纺织化学与染整工程专业论文.docxVIP

洗性能。但比较整理后织物的白度、断裂强力、回潮率、抗弯刚度、染色性等性 能，SiFR 均优于 PN-2。 关键词：真丝；阻燃；接枝；共价键；极限氧指数；耐洗性；白度 II Abstract The silk fabric belongs to flammable material because its limit oxygen index is only about 23%. So it can’t satisfy the flame retardant performance requirements of some markets. Now it also existed problems of poor washing fastness or easy yellowing when silk fabrics were finished by commercially flame retardant. Aiming at solving these problems, two kinds of flame retardant with reactive groups were designed in this paper. Vinyl nitrogen-phosphorus flame retardants and vinyl sulfone containing silicon flame retardant were synthesized. Based on principles of graft copolymerization between silk and vinyl and covalent bonding between silk and vinyl sulfone reactive radicals, two kinds of self-made flame retardant were finished to silk fabrics, and the application performance of the fabric after finishing were tested. Two kinds of vinyl nitrogen-phosphorus flame retardants were synthesized with phosphorus oxychloride, diethylamine (or diisopropylamine), hydroxyl ethyl methacrylate as main raw materials, ethyl acetate as solvent and triethylamine as acid binding agent. The synthesis of the target products were confirmed through fourier infrared spectrum, hydrogen nuclear magnetic resonance spectrum and mass spectrometry. The synthesis conditions of the intermediates and target product were optimized. Due to the grafting rate and limiting oxygen index of silk grafted by PN-2 were higher than that of PN-1, so the paper selected PN-2 flame retardant for further application. Then the effects of PN-2 parameters on grafting rate of silk fabric were investigated. And the LOI, washing fastness, physical and dyeing performance of the silk fabric treated by PN-2 were also tested. The results showed that the grafting rate was 15.4% and LOI was 31.2% in the optimal grafting process conditions, reaching the nonflammable level B1. LOI was still 30.9% after washing for 50 times, maintaining