反应条件对煤灰熔融特性的影响热能工程专业论文.docx

Abstract Coal takes a dominated part in China’s energy structure. This situation will not change in a long period. In China’ power industry, coal takes a large proportion and brings up lots of environment problems. The Clean Coal Technology (CCT) is an important gateway to realize the high efficient and clean utilizing of coal. Due to its high generating efficiency and excellent environment protection, Integrated Gasification of Combined Cycle (IGCC) becomes a significant development direction of CCT. The syngas cooler is a key equipment of IGCC systems. The fusion characteristics of coal ash are important factors which greatly influence the structure design of syngas cooler. There are a lot of minerals contained in coal, and their characteristics in high temperature are very complex. Many researchers have got a lot of results on the research of coal ash fusion under oxidizing and weakly reducing atmospheres. But there are less work done under the syngas atmosphere. The author got the samples of Yimin lignite ash under different atmosphere at various temperatures at the experimental platform set up by him. The phases and appearance analysis have been taken by XRD, SEM and EDX. The discrepancy has been explained too. Results show that there are great differences of phases and appearance between the heating up and temperature drop process. The major phases are quartz, anorthite, albite, anhydrite and hematite in the heating up process. They are formed by reactions and interactions of minerals in the coal ash. They are more involved in the reactions forming low temperature co-melt under the syngas atmosphere. The sinter level is much deeper at the same temperature, which leads to lower melting point. That means the fouling and slagging on the heating surface is more serious. Quartz is the major phase in the temperature drop process. The precipitation reaches a peak value at 1200℃. The precipitation has been restrained under the syngas atmosphere. There are less di