反应烧结SiC陶瓷材料的制备及其结构与性能-材料物理与化学专业论文.docxVIP

Reaction sintered SiC ceramic materials preparation, structure and properties ABSTRACT In recent years, advanced structural ceramics, represented by reaction sintered SiC ceramics, are widely used in the mechanical seal industry. In the petroleum, chemical industries, pumps, blenders and others usually work in the tough condition of high-temperature and high-pressure, corrosion and wear. Therefore, higher properties of the seal materials are required. In order to improve the properties of these ceramic materials, the preparation process of them should be optimized, and relationship between microstructure and properties should be clarified. Because wear resistance of the seal ceramics has great effect on the quality and servicing life of them, study on the wear resistance of the seal ceramics is very important. In this paper, fine SiC powder of 7 μm in diameter was chosen as raw materials. Dense SiC ceramic materials were prepared through a reaction sintering technique. Phases, microstructures, mechanical properties and fractograph ies of the reaction sintered SiC ceramics were studied, accordingly. Effects of main technical parameters on the microstructures and mechanical properties of the reaction sintered SiC ceramics were also investigated. In terms of the ring block type friction and wear experiment, the friction and wear properties of the reaction sintered SiC ceramics on the dry or oil lubrication conditions were studied, respectively. In this experiment, one kind of imported pressureless sintering SiC ceramic ring was used as the friction ring, and the reaction sintered SiC ceramics developed by the author’s group were used as the friction blocks. When the forming pressure of 117 MPa is applied, the SiC performs are excellent in which the SiC particles and the graphite nano-particles distribute uniformly with 3-dimensional connecting pores formed to ensure a great self-infiltration ability of the molten Si. The reaction sintered SiC ceramics have a high Si