反应沉淀一体式矩形环流生物反应器脱氮除磷研究-环境科学与工程专业论文.docxVIP

Classified Index: X703.1 U.D.C: 504 Dissertation for the Master Degree of Engineering STUDY ON THE NUTRIENTS REMOVAL IN REACTION-PRECIPITATION INTEGRATED RECTANGULAR AIRLIFT LOOP REACTOR Candidate: Wang Dandan Supervisor: Prof. Lin Chaolin Associate Supervisor: Prof. Chen Fuming Academic Degree Applied for: Master of Engineering Specialty: Environmental Science and Engineering Affiliation: Shenzhen Graduate School Date of Defence: December, 2009 Degree-Conferring-Institution: Harbin Institute of Technology 摘 要 反应沉淀一体式矩形环流生物反应器（Reaction-Precipitation Integrated Rectangular Airlift Loop Reactor, 简称 RPIR）具有较高的传质传氧效率，对有机 物的去除效果好。为提高 RPIR 的脱氮除磷能力，本研究采取投加填料的方式， 选取了两种生物填料：悬挂式组合填料和悬浮聚氨酯泡沫块填料，共进行了三 组试验：无填料试验、组合填料试验及悬浮填料试验，并考察了反应器运行的 最佳工况。 试验的结果表明，聚氨酯泡沫块填料更适用于RPIR。采用聚氨酯泡沫块作 为生物膜载体时，RPIR系统的最佳效果的工况参数为：HRT=5.0h， COD/TN = 10，DO = 1.0 mg/L，MLSS= 8000mg/L，污泥龄为 15 天左右，硫酸亚铁投配比 2+ n(Fe ):n(P)=1.5:1。在最优工况运行下，系统具有较好的有机物和氮、磷去除效 + 果，出水COD、NH4-N、TN、TP均可达到《城镇污水处理厂污染物排放标准》 GB18918-2002 中的 1A标准要求。 通过投加聚氨酯泡沫块填料，RPIR 系统形成了厌氧-缺氧-好氧的微环境， 实现了同时硝化反硝化的脱氮形式。脱氮效率受 DO 和 C/N 的影响最大：DO 低于 0.5mg/L 或高于 1.5mg/L 都会破坏系统的硝化与反硝化平衡；C/N 比维持 在 10 以上可保证反硝化的正常进行。 试验的过程显示，聚氨酯泡沫块与 RPIR 内混合液流态一致，环流不受阻 碍，不影响反应器传质效率。加入填料后，系统更加稳定，不易发生污泥膨胀， 耐冲击负荷能力增强。 本研究也说明，RPIR 具有较好的处理能力，占地少、投资省、运行费用低 且管理方便，具有较好的推广价值。 关键词: 环流生物反应器；一体式；同时硝化反硝化；生物填料 Abstract Reaction-Precipitation Integrated Rectangular Airlift Loop Reactor (RPIR) has high performance of mass transfer and excellent for organics removal. The main objective of this study is to investigate the performance of the RPIR in nutrient removal with anthysis on influence factors. Two kinds of packings-combined packings and suspended packings as biocarriers were tested and three tests have been done. The results demonstrated that suspended packings were more suitable for the RPIR than combined packings. When suspended packings-polyurethane foam boxes have been tested as biocarriers, the optimum operation conditions in the RPIR system were at the HRT of 5h, the COD/N ratio of 10,t