Rietvel全谱拟合在水雾化触媒粉末物相分析及氧含量测定中的应用.docVIP

Rietveld全谱拟合在水雾化触媒粉末物相分析及氧含量测定中的应用 龙郑易\张腾辉，王庆，王平江 (浙汗省冶金研究院冇限公司浙江省钎焊材料与技术重点实验室浙江亚通焊材冇限公司，杭州310030) 在不同工艺条件下通过髙压水雾化方法制备金刚心介成用FeNi30触媒粉末。利用X射线衍射法及Rietveld 全谱拟合对触媒合金粉末中的物相进行定性与定是分析，以Rietveld全谘拟合的氧化物含最來计算总的氣含最，并 与氧分析仪测试结來进行对比。结米农明水雾化FeNi30触媒合金粉末中的氧化物主要以Fe3O4与FeO的形式存在， 以Rietveld全谱拟合后鉍化物含觉计算出的总鉍含觉结釆定鉍仪的测试结米吻合较好，相对误差在3xl(T6以下，可 作为一种快速测定FeNi30触媒合金粉木屮有效成分与氧含量的方法。 关键词：Rietveld全谱拟合，FcNi30,触媒粉末，杳效成分，鉍含量 TF123； TQ164 A Application of rietveld whole powder pattern Htting in determination effective composition and oxygen content of catalyst alloy powder LONG Zheng-yi, ZHANG Teng-hui, WANGQing,, WANG Ping-jiang (Zhejiang Metallurgical Research Institute Co.，Ltd，Zhejiang Province Key Laboratory of Soldering Brazing Materials and Technology, Zhejiang Asia-General Soldering Brazing Material Co.，Ltd， Hangzhou 310030, China) Abstract： FeNi30 catalyst powder were prepared by high-pressure water atomization at different process conditions. Determine the nature and quantitative analysis were processed by X-ray powder diffraction and Rietveld whole pattern fitting method. The oxygen content of catalyst powder were calculated based on the oxide content and the calculate results were compared with oxygen analyzer. The results show that oxide mainly in the form of Fe3O4 and FeO existed in water atomized FeNi30 catalyst alloy powder，the total oxygen content calculate from oxide content after rietveld whole pattern fitting in good agreement with test results oxygen analyzer，The relative error is under 3io6, rietveld whole pattern fitting method can be used to rapid determination of effective composition and oxygen content in FeNi30 catalyst alloy powder. Key words: rietveld whole pattern fitting，FeNi30，catalyst powder, effective composition, oxygen contention 近年來，随着粉末触媒法合成金刚石技术的不断进步和推广，以及压机的大型化和精确控制系 统的完善，我国的人造金刚石产暈和质量人幅度提尚［h2］。早期合成金刚石所使川的粉末触媒主要足 采用快速凝间气雾化方法来进行制备，所得触媒合金粉末具科成分均匀无偏析、氧含:W:低，合成金 刚石品质高等优点而被广泛应用。近年来发展了快速凝岡水雾化方法制备触媒介金粉末，也然所得 *基金项目：浙江省钎焊材料与技术重点实验室建设资助项H (2008F3030) 通讯 ：龙郑易，工程师。电