单组分耐蒸煮油墨用硅烷改性聚氨酯连接料的合成与性能分析-高分子化学与物理专业论文.docx

安徽大学硕士论文Ab 安徽大学硕士论文 Abstract 单组分耐蒸煮油墨用硅烷改性聚氨酯连接料的合成与性能研究 单组分耐蒸煮油墨用硅烷改性聚氨酯连接料的合成与性能研究 III III IV IV Abstract Study on the Synthesis and Properties of Polyurethane Vehicle Modified with Silane of One-component Steam Resistance Ink Author: Wang zhen directed by professor Yang Jian-jun (Chemistry and Chemical Engineering College, Anhui University) The advantages of polyurethane ink are easy to operation, performance, stability, strong adhesion, gloss distinctions, good heat tolerance, and so on. It can be suitable for all kinds of printing, is developing rapidly. Polyurethane ink of steam resistance in China started relatively late, and the demand for polyurethane ink of steam resistance is increasing at home and in the world. Compared with developed countries, both the theoretical research or the product varieties and technology devices are very large gaps in the domestic. So the application of polyurethane ink of steam resistance is very urgent. The article is divided into three parts. In the first part, polester polyol of sebacic acid series was synthesized by the condensation polymerization of decanedioic acid and terephthalic acid with ethanediol,butanediol,hexanediol and neopently glycol,the chloride, four isobutyl titanate, phosphate as the catalys.Secondly, through the help of chemical analysis, the micro-structure of the sample was characterized by X-ray diffraction analysis (WAXD). The relationship between the ratio of pure and acid and the polycondensation was inspected, and the impacts of chemical composition on samples of the crystalline polyester were discussed, and the impacts of the PTA or new diol on the crystallization of polyester performance and heat resistance of the impact were studied. It is shown that the crystallinity and melting point of copolyesters decreased with increasing contents of terephthalic acid or neopentyl glycol respectively, and its heat-resistant properties are enhanced obviously. The introduction of the molecular structure of be