嵌段共聚物链结构不对称性对其调控共混体系相结构行为的影响-化学工程专业论文.pdf.docxVIP

摘要的效果越显著。对于PS／PMMA体系，不加入相相容剂时双连续结构组成窗口为 摘要 的效果越显著。对于PS／PMMA体系，不加入相相容剂时双连续结构组成窗口为 PS／PMMA=45／55—50／50；加入对称嵌段共聚物(PMMAllo-b．PSllo)缩小了体系的 双连续结构组成窗口；加入不对称嵌段共聚物(PMMAll0-b．PS433)扩大了体系的 双连续结构组成窗口到Ps／PMMA=20／80～30／70；加入不对称性更大的嵌段共聚物 (V(S．r-MMA)22trbPS320)更加扩大了体系的双连续结构组成窗口到 PS／PMMA=1 0／90---30／70． (3)研究了共混条件对共混体系相形态的影响．发现共混时间、共混剪切强 度、共混加料策略均不影响共混物相结构，只是影响共混物的特征尺寸． (4)通过比较双连续结构共混物的退火粗化速率，研究了不对称嵌段共聚物 的序列结构对其界面活性的影响。相同分子量和单体组成下，纯两嵌段共聚物 (PMMAllo-b．PS433)界面活性最高，带有线性梯度嵌段的复合嵌段共聚物 (P(S．g．MMA)202-b．PS344)次之，带有无规共聚嵌段的复合嵌段共聚物 (P(S．r-MMA)220-b．PS320)界面活性最低．通过静态热处理的方法可以方便的在 0．19rn到约5岬的尺度上调控双连续结构的特征尺寸． (5)通过比较双连续结构共混物的拉伸力学性能，研究了不对称嵌段共聚物 的序列结构对其界面增强效果的影响。相同分子量和单体组成下，带有线性梯度 嵌段的复合嵌段共聚物(P(S．g．MMA)202．b．PS344)对PS／PMMA相界面增强效果最 佳，带有无规共聚嵌段的复合嵌段共聚物(P(S．r-MMA)220-b．PS320)次之，纯两嵌 段共聚物(PMMAllo．b．PS433)再次之。 关键词：双连续，不对称性，共混，相相容剂 Il 摘要Abstract 摘要 Abstract Polymer composites with CO·-continuous morphology on sub·—micrometer scale have very wide applications in various areas because of the special structure and performance． In the past decades，the preparation of such composites is attracting wider and wider research interests．Now,there are several ways to prepare the CO—continuous polymer composites Oil sub—micrometer scale．Among them，melt processing of two immiscible polymers is the simpliest one．In this method,one needs to add copolymers as compatibilizers to reduce the domain size down to sub-micrometer scale．However,the addition of the copolymers will increase the onset eompositon of the minor phase to form the CO．continuous structure and narrow the CO．continuous interval． In this thesis，we proposed a new way to overcome the above paradox under the inspirations from comparing、析nl the small molecular water-oil-emulsifier systems．To introduce asymmetric into the chain structure of the copolymers used as compatibilizers t could reduce the size of the minor phase domains，lower the onset of the CO．continuous structure，and broaden the CO·continuous interval simultaneously．The easy,effective， economic．and relia