含PNIPAM链段多嵌段聚合物的合成、溶液和吸附行为研究-高分子化学与物理专业论文.docxVIP

浙江大学硕士学位论文LCST时都会发生异常的大量吸附现象。结合之前在PNIPAM．PEO．PPO．PEO— 浙江大学硕士学位论文 LCST时都会发生异常的大量吸附现象。结合之前在PNIPAM．PEO．PPO．PEO— PNIPAM五嵌段聚合物的吸附研究中也发现五嵌段聚合物在PNIPAM链段的 LCST处发生大量吸附现象，可以得出以下结论：对于含PNIPAM链段的PEO． PMPAM、PNIPAM．PPO．PNIPAM和PNIPAM．PEO．PPO．PEO—PNIPAM嵌段聚合 物体系，所观察到的大量吸附现象与PNIPAM链段存在有关，与PPO链段和PEO 链段无关；而且嵌段聚合物分子中PNIPAM链段需要达到一定的长度，使得 PNIPAM链段具有自己的LCST，PNIPAM链段太短则不会发生大量吸附。 关键词：PNIPAM—PPO．PNIPAM，PEO．PNIPAM，温敏性，链构象，吸附行为 万方数据 浙江大学硕士学位论文 浙江大学硕士学位论文 ABSTRACT Poly(N-isopropylacrylamide)一poly(ethyleneoxide)-poly(N-isopropylacrylamide) (PNIPAM-PPO—PNIPAM)triblock copolymers with ilarrow molecular weight distribution were successfully synthesized by one or two steps of polymerization via atom transfer radical polymerization(ATRP)，with Br-PPO-Br as macro-initiator． Micro—differential scanning calorimetry(Micro—DSCl was used to determine the thermo—sensitive behavior of PNIPAMx—PP036-PNIPAMx triblock copolymers and PE045-PNIPAMx diblock copolymers．It was found that the PNIPAM block with x=15 was too short to maintain its 0wa LCST(10wer critical solution temperature)，SO that only LCST of PPO block was observed，i．e．250C，for PNIPAMl5-PP036-PNIPAMl5 in dilute aqueous solution．For the longest PNIPAM block with x=117，only LCST of PNIPAM block dominated，i．e．32．3。C．With middle length X，PNIPAM33-PP036一 PNIPAM33 and PNIPAM75一PP036-PNIPAM75 exhibited two LCSTs，which were corresponding to LCSTs of PPO and PNIPAM blocks，respectively．While it comes to PEO-PNIPAM diblock copolymers，as the PEO block is hydrophilic，the LCST of the copolymer is relatively higher than that of PNIPAM homopolymer and the higher content of PEO block is，the higher LCST is．The chain conformations of the copolymers were then studied with static and dynamic light scattering(DESSLS)．It was observed that“associate”structures formed in dilute aqueous solutions of PN／PAM_x·-PP036·-PNIPAMx triblock copolymers and PE04s·-PNIPAMx diblock copolymers at low temperature(i．e．200C)，at which temperature PPO，PNIPAM and PEO segments are theoretica