固化动力学及其计算机处理系统的实现-材料学专业论文.docxVIP

。一 。一Study on curing kinetic and its computer dealing system Abstraet The paper introduces the history and importance of the curing kinetic studies， then the author gives the analyses to several important curing kinetic methods by his experience of dealing with curing data and information from relative literatures．The author also expatiates on the application premise，suppose condition and curing model to every curing method． The author makes a simple curing dealing software by VBA language．W1th the help of the software，the user can deal with the data conveniently based on the Kissinger method；however,complex function is not reachable because of the VBA language’S problem itselE The emphasis of this paper is put upon a VB program“curing kinetic operating system”programmed by the author with ten．thousand．1ines codes．The sottware realized the aim of design by using some new methods and new arithmetic with clear program structure and friendly user interface．The sol,ware provides six methods to its user,including Kissinger method，Ozawa method，Freeman-Carroll method， Zavkovik method，Extrapolate method and Satava-Sestak method．Users Carl choose appropriate methods from them and use them to deal with different curing systems． On the other hand，there are some useful tools in the software，such躯plot tool and phase fit tool etc． The software，Curing kinetic dealing system，was applied to analyze Epoxy／TOA／Org-MMT curing system and Epoxy／DETA／Org-MMT curing system， Both initial curing temperature and final temperature of two systems moved to the peak temperature of the systems with addition of Org·MMT,and the peak temperatures were ke：pt constant．As to Epoxy厂r0～Org-MMT system，the reaction order was 0．9 and active energy WaS 66kJ／mol by Kissinger method；and a similar result was obtained by Ozawa method．The curing reaction WaS controlled clearly bv dim】sion mechanism in t11e 1ater stage of curing reaction without addition of Org-MMT．which leads to the increment ofactive energy with