萃取法富集蓖麻油酸甲酯工艺研究.pdfVIP

2016 年第 29 卷第 1 期 粮食与油脂 45 萃取法富集蓖麻油酸甲酯工艺研究 李修冒，崔建兰，雒冬梅 （中北大学化工与环境学院，　山西太原　030051 ） 摘　要：采用两种液液萃取的方法对蓖麻油酸甲酯的提纯进行了研究，原料直接萃取法采用石油 醚（60~90 ℃）和90% （体积比）甲醇水溶液的混合物做萃取剂从蓖麻油甲酯混合物中萃取得到 蓖麻油酸甲酯，收率达到86% 以上，质量分数达到97% 以上。葵花油添加萃取法采用90% 甲醇 水溶液从蓖麻油甲酯和精炼葵花油的混合物中萃取得到蓖麻油酸甲酯，收率同样达到86% 以上， 质量分数达到94% 以上。实验表明两种方法收率一致，而原料直接萃取法操作复杂，所得蓖麻油 酸甲酯质量分数高，葵花油添加萃取法操作简单，所得蓖麻油酸甲酯质量分数相对低。 关键词：蓖麻油酸甲酯；萃取；石油醚；甲醇水溶液；葵花油 Study on the technology of the enrichment of methyl ricinoleate by extraction LI Xiu-mao ，CUI Jian-lan ，LUO Dong-mei （School of Chemical and Environmental Engineering ，North University of China ，Taiyuan 030051 ，Shanxi ，China ） Abstract ：Purifying methgl ricinoleate were studied by two kinds of liquid–liquid extraction. Direct extraction of the raw material used the mixture of petroleum ether （60~90 ℃） and 90% aqueous methanol （volume ratio ）to purify methyl ricinoleate from castor oil methyl esters. The yield reached more than 86% ，and the mass fraction reached more than 97%. The extraction of adding the sunflower oil used 90% aqueous methanol to purify methyl ricinoleate from castor oil methyl esters and refined sunflower oil. The yield reached more than 86% ，and the mass fraction reached more than 94%. The experimental results indicated that yields of the two methods were equal ，however ，the operation of direct extraction of the raw material was complicated ，the mass fraction of methyl ricinoleate was higher ，and the operation of the extraction of adding the sunflower oil was simple ，the mass fraction of methyl ricinoleate was lower. Key words ：methyl ricinoleate ；extraction ；petroleum ether ；aqueous methanol ；sunflower oil 中图分类号：TS229 文献标识码：A 文章编号：1008―9578（2016）01―0045―04 蓖麻起源于非洲，是一种重要的油